Lubricant Additives

(Kiana) #1

118 Lubricant Additives: Chemistry and Applications



  1. U.S. Patent 3,658,706, Ethyl Corp., 1972.

  2. Goode, M.J., W.D. Phillips. Triaryl phosphate ester hydraulic fl uids-A reassessment of their toxicity and
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  3. Henschler, D., H.H. Bayer. Toxicological studies of triphenyl phosphate, trixylenyl phosphate and
    triaryl phosphates from mixtures of homologous phenols. Arch Exp Pathol Pharmakol 233: 512 –517,



  4. Mackerer, C., M.L. Barth, A.J. Krueger. A comparison of neurotoxic effects and potential risks from
    oral administration or ingestion of tricresyl phosphate and jet engine oil containing tricresyl phosphate.
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  5. Daughtrey, W., R. Biles, B. Jortner, M. Ehrlich. Delayed neurotoxicity in chickens: 90 day study with
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  6. Du rad® 310M, Great Lakes Chemical Corp., May 2002.

  7. Drake, G.L., Jr., T.A. Calamari. Industrial uses of phosphonates. In Role of Phosphonates in Living
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  8. Roby, S.H., J.A. Supp. Effects of ashless antiwear agents on valve train wear and sludge formation in
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  9. Devlin, M.T., R. Sheets, J. Loper, G. Guinther, K. Thompson, J. Guevremont, T.-C. Jao. Effect of ashless
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  10. Traut wei n, W.-P. AdBlue as a Reducing Agent for the Decrease of NOx Emissions from Diesel Engines
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  11. U.S. Patent 5,630,852, FMC Corp., 1997.

  12. Crosby, G.W., E.W. Brennan. Am Chem Soc Div Petrol Chem, Preprints 3(4A): 171, 1958.

  13. Demizu, K., H. Ishigaki, M. Kawamoto. The effect of trialkylphosphites and other oil additives on the
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  14. German Patent 1,271,874, Hüls Chemicals. 1968.

  15. German Patent 1,286,675, Hüls Chemicals. 1969.


APPENDIX A: EARLY PATENT LITERATURE ON PHOSPHORUS-


CONTAINING COMPOUNDS

NEUTRAL PHOSPHATES


U.S. Patent 2,723,237, Texas Oil Co.


NEUTRAL PHOSPHITES


As AW/EP Additives
British Patent 1,052,751, British Petroleum (chlorethyl phosphite and a chlorparaffi n)
British Patent 1,164,565, Mobil Oil Corp. (alkyl or alkenyl phosphite and a fatty acid ester)
British Patent 1,224,060, Esso Research and Engineering Co.
U.S. Patent 2,325,076, Atlantic Refi ning Co.
U.S. Patent 2,758,091, Shell Development Co. (haloalkyl or haloalkarylphosphites)
U.S. Patent 3,318,810, Gulf Research & Development Co. (phosphites and molybdenum compounds)


As Antioxidants


U.S. Patent 2,326,140, Atlantic Refi ning Co.
U.S. Patent 2,796,400, C.C. Wakefi eld & Co.


ACID PHOSPHATES/PHOSPHITES


British Patent 1,105,965, British Petroleum Co Ltd. (acid hydrocarbyl phosphite and phosphates or thiophos-
phates or phosphoramidates)

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