118 Lubricant Additives: Chemistry and Applications
- U.S. Patent 3,658,706, Ethyl Corp., 1972.
- Goode, M.J., W.D. Phillips. Triaryl phosphate ester hydraulic fl uids-A reassessment of their toxicity and
environmental behaviour. SAE Paper 982004, 1998. - Henschler, D., H.H. Bayer. Toxicological studies of triphenyl phosphate, trixylenyl phosphate and
triaryl phosphates from mixtures of homologous phenols. Arch Exp Pathol Pharmakol 233: 512 –517,
- Mackerer, C., M.L. Barth, A.J. Krueger. A comparison of neurotoxic effects and potential risks from
oral administration or ingestion of tricresyl phosphate and jet engine oil containing tricresyl phosphate.
J Toxicol Environ Health, Part A 57(5): 293–328, 1999. - Daughtrey, W., R. Biles, B. Jortner, M. Ehrlich. Delayed neurotoxicity in chickens: 90 day study with
Mobil Jet Oil 254. The Toxicologist, 90, Abstract 1467, 2006. - Du rad® 310M, Great Lakes Chemical Corp., May 2002.
- Drake, G.L., Jr., T.A. Calamari. Industrial uses of phosphonates. In Role of Phosphonates in Living
Systems, ed. R. Hildebrand. Boca Raton, FL: CRC Press, 1983. - Roby, S.H., J.A. Supp. Effects of ashless antiwear agents on valve train wear and sludge formation in
gasoline engine testing. Lubr Eng 53(11): 17–22, 1977. - Devlin, M.T., R. Sheets, J. Loper, G. Guinther, K. Thompson, J. Guevremont, T.-C. Jao. Effect of ashless
phosphorus antiwear compounds on passenger car emissions and fuel effi ciency. Additives 2007 Conf.,
London, April 2007 - Traut wei n, W.-P. AdBlue as a Reducing Agent for the Decrease of NOx Emissions from Diesel Engines
of Commercial Vehicles, Research Report 616-1, DGMK, Hamburg, 2003. - U.S. Patent 5,630,852, FMC Corp., 1997.
- Crosby, G.W., E.W. Brennan. Am Chem Soc Div Petrol Chem, Preprints 3(4A): 171, 1958.
- Demizu, K., H. Ishigaki, M. Kawamoto. The effect of trialkylphosphites and other oil additives on the
boundary friction of oxide ceramics against themselves and other metals. Tr ib In tl 30(9): 651– 657, 1997. - German Patent 1,271,874, Hüls Chemicals. 1968.
- German Patent 1,286,675, Hüls Chemicals. 1969.
APPENDIX A: EARLY PATENT LITERATURE ON PHOSPHORUS-
CONTAINING COMPOUNDS
NEUTRAL PHOSPHATES
U.S. Patent 2,723,237, Texas Oil Co.
NEUTRAL PHOSPHITES
As AW/EP Additives
British Patent 1,052,751, British Petroleum (chlorethyl phosphite and a chlorparaffi n)
British Patent 1,164,565, Mobil Oil Corp. (alkyl or alkenyl phosphite and a fatty acid ester)
British Patent 1,224,060, Esso Research and Engineering Co.
U.S. Patent 2,325,076, Atlantic Refi ning Co.
U.S. Patent 2,758,091, Shell Development Co. (haloalkyl or haloalkarylphosphites)
U.S. Patent 3,318,810, Gulf Research & Development Co. (phosphites and molybdenum compounds)
As Antioxidants
U.S. Patent 2,326,140, Atlantic Refi ning Co.
U.S. Patent 2,796,400, C.C. Wakefi eld & Co.
ACID PHOSPHATES/PHOSPHITES
British Patent 1,105,965, British Petroleum Co Ltd. (acid hydrocarbyl phosphite and phosphates or thiophos-
phates or phosphoramidates)