Synthetic Inorganic Chemistry

(John Hannent) #1
178 NON-METALLIC ELEMENTS IN BINARY COMPOUNDS


  1. Many binary compounds of non-metals with non-metals
    are known, but such compounds usually can exist only out of
    contact with water. For example, phosphorus trichloride is
    completely hydrolyzed by water. Write the equation for this
    reaction, and treating it as a metathesis, conclude which element
    in the phosphorus trichloride is to be regarded as the positive
    constituent.

  2. Arrange the non-metals studied in this chapter in the order
    of their activity as negative elements, (a) when they react in
    aqueous solution, (b) when they react with "dry" substances.

  3. Look up the heat of solution of hydrogen iodide and hydrogen
    sulphide, and state how this factor is able to make iodine more
    active than sulphur in aqueous solution, whereas sulphur is the
    more active in the dry state.

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