PHYSICAL CHEMISTRY IN BRIEF

(Wang) #1
CONTENTS [CONTENTS] 21

11.8.7 Nernst equation for a half-cell........................ 402
11.8.8 Electromotive force and electrode potentials................ 402
11.8.9 Classification of half-cells........................... 403
11.8.10Examples of half-cells............................. 403
11.8.10.1 Amalgam half-cell......................... 404
11.8.10.2 Half-cell of the first type...................... 404
11.8.10.3 Half-cell of the second type.................... 404
11.8.10.4 Gas half-cell............................. 405
11.8.10.5 Reduction-oxidation half-cell................... 406
11.8.10.6 Ion-selective half-cell........................ 406
11.8.11Classification of galvanic cells........................ 407
11.8.12Electrolyte concentration cells with transference.............. 408
11.8.13Electrolyte concentration cells without transference............ 408
11.8.14Gas electrode concentration cells...................... 409
11.8.15Amalgam electrode concentration cells................... 410
11.9 Electrode polarization................................ 411

12 Basic terms of chemical physics 412
12.1 Interaction of systems with electric and magnetic fields.............. 412
12.1.1 Permittivity.................................. 412
12.1.2 Molar polarization and refraction...................... 414
12.1.3 Dipole moment................................ 414
12.1.4 Polarizability................................. 415
12.1.5 Clausius-Mossotti and Debye equations................... 416
12.1.6 Permeability and susceptibility....................... 417
12.1.7 Molar magnetic susceptibility........................ 418
12.1.8 Magnetizability and magnetic moment................... 418
12.1.9 System interaction with light........................ 419
12.2 Fundamentals of quantum mechanics........................ 421
12.2.1 Schr ̈odinger equation............................. 421
12.2.2 Solutions of the Schr ̈odinger equation.................... 421
12.2.3 Translation.................................. 422
12.2.4 Rotation.................................... 423

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