inorganic chemistry

S
Salicylurate (SU), 28
Selectivity and regulation
catalytic activity controlling,
258 – 259
controlling reaction pathways,
257 – 258
Solar photocatalysts.SeeTransition
metal complexes
Spectral sensitization
aspects, 248
bacteriochlorophyll a, electronic
spectrum, 249f
photosensititzer Ru(bpy) 32 þ,
250 – 251, 251f
porphyrins, 248
Spin-catalysis, 256
SU.SeeSalicylurate (SU)
Synergetic effects, 423– 425

T
Titania–chloroplatinum(IV) complexes
diffuse reflectance spectra, 380f
mechanism, 383– 384
photodegradation,
381 – 382artificial visible light,
381 – 382, 382f
indoor and outdoor daylight,
382 – 383, 383f
preparation and characterization,
379 – 381
recorded photovoltage, 381f
sol-gelmethods,PtCl 4 units,378– 379

Titania–halogenorhodium(III)

complexes

characterization, 385– 387

diffuse reflectance spectra,

386f, 387f

mechanism, 389– 391

photocatalytic activity, 387– 388

Transition metal complexes

atmospheric gas conversion

nitrogen oxides, 302– 315

VOCs, 300– 302

environmental compartments

complexation effects, 296– 299

sunlight, 293– 296

hydrosphere and soils, 316– 333

Two-electron redox relays, 262– 263

V

Visible light photocatalysis

cocatalyst loading, 419– 420

doping, 415– 416

titania–chloroplatinum(IV)

complexes, 378– 384

titania-halogenorhodium(III)

complexes, 384– 391

Volatile organic compounds (VOCs),

300 – 302

W

Water photochemical splitting

cyclic process, 353

FeIIIOFeIIImoiety, 348

osmocene, 349– 353

INDEX 439