Nucleic Acids in Chemistry and Biology

(Rick Simeone) #1

encoded by a gene and to determine its levels of transcription and tissue specificity. Methods exist for both
of these purposes and both depend upon the ability of a single-stranded nucleic acid to pair specifically
with its complementary strand.


5.5.1 Parameters that Affect Nucleic Acid Hybridisation

Hybridisation is the annealing of two single strands of a nucleic acid to form a duplex. Duplex strength is
measured by observation of the melting temperature(Tm) and is affected by several parameters.


5.5.1.1 Base Composition (%GC). Since G–C base pairs have three hydrogen bonds, they are


stronger than A–T base pairs, which have only two. Thus duplexes with higher G–C content have higher
melting temperatures.


5.5.1.2 Temperature (T). The rate of association of single-stranded DNA into a duplex varies


markedly with temperature (Figure 5.9: see also Section 2.5.1). The shape of this curve is governed by two


Nucleic Acids in Biotechnology 179


Figure 5.8 Gene synthesis by recursive PCR. Bars represent oligonucleotides and their extension products
after PCR

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