Molecular Design of Novel Self-Oscillating
Polymer Chains Fuelled by Organic Acid Under Constant Condition
283
Fig. 4. Chemical structure of poly(NIPAAm-co-Ru(bpy) 3 -co-MAPTAC).
Transmittance%[]Time S[ ] Time S[ ]Transmittance%[]15 C
。
21 C
。
27 C
。
33 C
。
39 C
。
45 C
。
Transmittance%[]Transmittance%[]Time Time S[S[S[ ]]] Time Time S[S[S[ ]]]Transmittance%[]Transmittance%[]15 C
。
15 C。
21 C
。
21 C。
27 C
。
27 C。
33 C
。
33 C。
39 C
。
39 C。
45 C
。
45 C。
Fig. 5. Oscillating profiles of the optical transmittance for poly-(NIPAAm-co-Ru(bpy) 3 -co-
MAPTAC) solutions at several constant temperatures (15, 21, 27, 33, 39 and 45 °C).
(Reprinted ref. 38, Copyright American Chemical Society. Reproduced with permission.)