Molecular Design of Novel Self-Oscillating
Polymer Chains Fuelled by Organic Acid Under Constant Condition
293
0
1
2
3
4
5
6
7
0 500 1000 1500 2000 2500 3000 3500 4000
Time 【S 】
Transmittance
【
%
】
0
1
2
3
4
5
6
7
0 500 1000 1500 2000 2500 3000 3500 4000
Time 【S 】
Transmittance
【
%
】
(C)
Fig. 11. Oscillating profiles of the optical transmittance for the poly(NIPAAm-co-Ru(bpy) 3 -
co-AMPS-co-MAPTAC) solutions at 12 °C for several concentrations of malonic acid:
(A) [MA] = 0.3 M, (B) [MA] = 0.5 M, (C) [MA] = 0.7 M. (Reprinted ref. 39, Copyright
American Chemical Society. Reproduced with permission.)
199s
161s
121s
0
50
100
150
200
250
0.3 0.5 0.7
[MA] / M
Time
【
S
】
199s
161s
121s
0
50
100
150
200
250
0.3 0.5 0.7
[MA] / M[MA] / M
Time
【
S
】
Fig. 12. Dependence of the period on the concentration of malonic acid for the
poly(NIPAAm-co-Ru(bpy) 3 -co-AMPS-co-MAPTAC) solutions at 12 °C. (Reprinted ref. 39,
Copyright American Chemical Society. Reproduced with permission.)