242 12 Phospholipases Used in Lipid Transformations
Table 3.Head groups introduced by PLD into 1,2-diacyl-sn-glycerophospholipids.
Head group
introduced
Educt^1 Source of PLD Solvent system ReferenceAliphatic primary
alcohols
PC (egg yolk) Cabbage acetate buffer/SDS Dawson, 1967PC Savoy cabbage acetate buffer/
diethyl etherYang et al., 1967PC (egg yolk),
DLPC, DMPC,
DPPC and otherCabbage acetate buffer/
diethyl etherEibl and Kovatchev,
1981DMPC, DPPC Cabbage acetate buffer/
diethyl etherSale et al., 1989PC (egg yolk) Streptomycessp.
(PLD lipid-coated)acetate buffer/
benzeneOkahata et al., 1995Unsaturated
propanols
PC (egg yolk) Cabbage acetate buffer/
diethyl etherKovatchev and Eibl,
1978Halogenethanols PC (egg yolk) Cabbage acetate buffer/
diethyl ether
Kovatchev and Eibl,
19783,3,-Dimethyl-
1-butanol
DHPC Streptomycessp. acetate buffer/
chloroformMartin and Hergen-
rother, 1998bAliphatic
secondary alcohols
(Figure 13A)
PC Streptomycessp. acetate buffer/
ethyl acetate or
methylene chlorideD’Arrigo et al., 1994Ethylene glycol PC (egg yolk) Cabbage acetate buffer/SDS Dawson, 1967
Higher alkandiols PC (egg yolk) Cabbage acetate buffer/
diethyl ether
Kovatchev and Eibl,
1978Glycerol PC (egg yolk) Cabbage acetate buffer/SDS Dawson, 1967
PC Savoy cabbage acetate buffer/
diethyl etherYang et al., 1967PC Cabbage acetate buffer/
diisopropyl ether
or other (in a mi-
croporous mem-
brane reactor)Lee et al., 1985PC Cabbage acetate buffer/
diethyl ether
(micelles or
emulsion systems)Juneja et al., 1987aPC Cabbage
(PLD immobilized)acetate buffer/
diethyl etherJuneja et al., 1987bDihydroxyacetone DPPC Streptomycessp. acetate buffer/
ethyl acetate
Takami and Suzuki,
1994