Front Matter

17.2 Lipase- and protease-catalyzed esterification of lipids 371

Table 3.

Lipase-catalyzed glycolipid syntheses using alkyl glycosides.

Lipase

Solvent

Log

P

Lipid Reactant

Modified Sugar

Reference

Candida antarctica

1

C

8:0

C

18:0

,C

18:1

Ethyl

D

-glucopyranoside,

Bjo

̈rkling et al., 1989;

Humicola

spec.

1

i-Propyl

D

-glucopyranoside,

Kirk et al., 1992;

Mucor miehei

1

n-Propyl

D

-glucopyranoside,

Andresen and Kirk, 1995

n-Butyl

D

-glucopyranoside

Candida antarctica

1

Benzene/Pyridine

þ

2.00/ Methyl oleate

Methyl glucoside,

Mutua and Akoh, 1993

(2/1, v/v)

þ

0.71

Methyl galactoside,Octyl galactoside

Candida antarctica

1

Benzene/Pyridine

þ

2.00/ Methyl oleate,

Methyl glucoside,

Akoh and Mutua, 1994

(2/1, v/v)

þ

0.71

Eicosapentaenoic acid,

Methyl galactoside,

Docosahexaenoic acid

Octyl galactoside

Candida antarctica

1

t-Butanol

þ

0.80

Ethyl propionate,Ethyl decanoate

Methyl- to Dodecyl-glucoside/fructoside/galactoside

Goede de et al., 1994

Pseudomonas cepacia

Acetonitrile

0.33

Octanoic acid

Methyl

a

• D

-galactopyranoside

Co

́rdova et al., 1997

Candida antarctica

1

Dodecanoic acid

3-Chloropropyl

D

-glucopyranoside Kirk et al., 1998

Porcine pancreas

e

-Caprolactone

a,

b-Ethyl glucopyranoside

Bisht et al., 1998

Candida antarctica

1

Trimethylene carbonate

a,

b-Ethyl glucopyranoside

Bisht et al., 1998

Candida antarctica

1

2-Methyl-2-butanol;

þ

1.30

Oleic acid

a-

D

-Butyl glucoside

Bousquet et al., 1999

Rhizomucor miehei

1

solvent-free

1

Immobilized enzymes.