Polyelectrolytes: Theory, Properties and Applications

(Ron) #1

RELATED NOVA PUBLICATIONS


PHASE TRANSITIONS IN WATER-IN-WATER


BSA/DEXTRAN EMULSION IN THE PRESENCE


OF STRONG POLYELECTROLYTE*


Y. A. Antonov^1 , and P. Moldenaers^2


(^1) N. M. Emanuel Institute of Biochemical Physics,
Russian Academy of Sciences, Moscow, Russia
(^2) K. U. Leuven, Department of Chemical Engineering,
Leuven, Belgium
We examine whether a small amount of strong polyelectrolyte (dextran
sulfate sodium salt /DSS/) can induce mixing of BSA and dextran in
aqueous water-in-water BSA/dextran emulsion and how intermacromolecular
interactions affect its rheological properties.
Addition of DSS to water-in-water emulsion at pH 5.4 leads to its mixing,
a noticeable increase in viscosity and module (G). Mixing is observed at the
DSS/BSA weight ratio, qBSA  0.07. Increasing the ionic strength in the
resulting single-phase system induces phase separation. Our results show that



  • The full version of this chapter can be found in News in Chemistry, Biochemistry and
    Biotechnology: State of the Art and Prospects of Development, edited by Gennady E.
    Zaikov, Grzegorz Nyszko, Larisa P. Krylova and Sergei D. Varfolomeev, published by
    Nova Science Publishers, Inc, New York, 2014.
     Corresponding author:Yurij A. Antonov e-mail:[email protected]

Free download pdf