Physical Chemistry Third Edition

...

Physical Chemistry Third Edition ...

...

Physical Chemistry Third Edition Robert G. Mortimer Professor Emeritus Rhodes College Memphis, Tennessee AMSTERDAM•BOSTON•HEIDEL ...

Cover Design: Eric DeCicco Cover Image: © iStockphoto Elsevier Academic Press 30 Corporate Drive, Suite 400, Burlington, MA 0180 ...

To my wife, Ann, and to my late father, William E. Mortimer, who was responsible for my taking my first chemistry course ...

...

Contents Periodic Table Inside front cover List of Numerical Tables in Appendix A Inside front cover Information Tables Inside b ...

viii Contents ...

Contents ix Part 2 Dynamics 381 Chapter 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at Equilibrium 383 9.1 Macros ...

x Contents ...

Contents xi 18.6 The Lithium Atom 781 18.7 Atoms with More Than Three Electrons 784 Chapter 19 The Electronic States of Atoms. I ...

xii Contents 23.5 Spectra of Polyatomic Molecules 975 23.6 Fluorescence, Phosphorescence, and Photochemistry 979 23.7 Raman Spec ...

Contents xiii - Entropy 3.2 The Mathematical Statement of the Second Law: 3.3 The Calculation of Entropy Changes 3.4 Stati ...

...

Preface This is the third edition of a physical chemistry textbook designed for a two-semester undergraduate physical chemistry ...

xvi Preface The author encourages students and instructors to comment on any part of the book; please send comments and suggesti ...

Acknowledgments The writing of the first edition of this book was begun during a sabbatical leave from Rhodes College, and conti ...

...

1 Thermodynamics and the Macroscopic Description of Physical Systems ...