Physical Chemistry Third Edition

502 11 The Rates of Chemical Reactions When the expressions forGandHare substituted into Eq. (11.3-10) and the resulting express ...

11.3 Forward Reactions with More Than One Reactant 503 The first term on the right-hand side of this equation has the same value ...

504 11 The Rates of Chemical Reactions kf rinitial [NO]^2 [Cl 2 ]  (7. 1 × 10 −^5 mol L−^1 s−^1 ) (0.0200 mol L−^1 )^2 (0.0200 ...

11.3 Forward Reactions with More Than One Reactant 505 Not only is the concentration of H 2 O nearly constant, but the concentra ...

506 11 The Rates of Chemical Reactions to obtain the result kt ( 1 [B] 0 −[A] 0 )( 1 [A] − 1 [A] 0 ) + 1 ([B] 0 −[A] 0 )^2 ln ( ...

11.4 Inclusion of a Reverse Reaction. Chemical Equilibrium 507 11.4 Inclusion of a Reverse Reaction. Chemical Equilibrium If the ...

508 11 The Rates of Chemical Reactions We can express [B] in terms of [A]. Assume that initially only substance A is present so ...

11.4 Inclusion of a Reverse Reaction. Chemical Equilibrium 509 EXAMPLE11.11 For a hypothetical isomerization that is first order ...

510 11 The Rates of Chemical Reactions a.Integrate the rate differential equation for the case that the initial concentrations o ...

11.5 A Simple Reaction Mechanism: Two Consecutive Steps 511 The solution of this equation is carried out in Appendix B for the c ...

512 11 The Rates of Chemical Reactions thatk 1  0 .500 s−^1 andk 2  0 .100 s−^1 .Ifk 1 <k 2 , the amount of B remains relat ...

11.6 Competing Reactions 513 PROBLEMS Section 11.5: A Simple Reaction Mechanism: Two Consecutive Steps 11.32For the consecutive ...

514 11 The Rates of Chemical Reactions We have d[F] dt k 1 [A]k 1 [A] 0 e−(k^1 +k^2 )t (11.6-5) The right-hand side of this eq ...

11.7 The Experimental Study of Fast Reactions 515 PROBLEMS Section 11.6: Competing Reactions 11.36Consider the competing reactio ...

516 11 The Rates of Chemical Reactions Light source Monochromator Reservoir Light beam syringes Stop syringe Device for driving ...

11.7 The Experimental Study of Fast Reactions 517 Oscilloscope Monochromator PM Sample Analyzing light source Flash lamp Spark g ...

518 11 The Rates of Chemical Reactions [C] [A] [B] [B] 0 [A] 0 [C] 0 Concentration t 50 Time Figure 11.9 The Behavior of a Syste ...

11.7 The Experimental Study of Fast Reactions 519 Exercise 11.23 a.Verify the steps of algebra leading to Eq. (11.7-7). b.Verify ...

520 11 The Rates of Chemical Reactions K 1  k 1 k′ 1  [H 2 O]^2 [ H+ ][ OH− ] (55.35 mol L−^1 )^2 1. 008 × 10 −^14 mol^2 L−^2 ...

11.7 The Experimental Study of Fast Reactions 521 second order and the reverse reaction to be first order. c.Find the expression ...