The Chemistry Maths Book, Second Edition

(Grace) #1

288 Chapter 9Functions of several variables


The general case


The transformation from cartesian to polar coordinates is a special case of the general


transformation of variables (of coordinate system). It is also the most important in


practice, and only a brief discussion of the general case is given here. Let


x 1 = 1 x(u, 1 v), y 1 = 1 y(u, 1 v) (9.61)


be continuous and differentiable functions of the variables uand v, such that for each


point(x,y)in a region R of the xy-plane there corresponds a unique point(u, 1 v)in


the corresponding region R*of the uv-plane. Then


(9.62)


where|J|is the modulus of the Jacobianof the transformation,


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(9.63)


For example, ifx 1 = 1 r 1 cos 1 θandy 1 = 1 r 1 sin 1 θthen


anddA 1 = 1 dxdy 1 → 1 dA 1 = 1 rdrdθ, as obtained geometrically from Figure 9.16. The Jacobian


is used in advanced formulations of thermodynamics for the transformation of


thermodynamic variables. The method can be generalized for three or more variables.


The integral


It was stated in Example 6.16 of Section 6.5 that this integral cannot be evaluated by


the methods described in Chapters 5 and 6. It can however by evaluated by means of


a ‘trick’ involving the transformation of a double integral from cartesian to polar


coordinates.


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We have


because the integral is an even function of x(see Section 5.3). Also


Iedy


y

=




1


2


2

Z




Iedx edx


xx

==





ZZ


0

22
1

2





Z


0

2


edx


−x

J


x


r


yxy


r


= rrr











=+=


θθ


cos θθsin


22

J


xy


u


x


u


yxy


u


=


∂,


∂,


=











()


()vvv


ZZ ZZ


RR*

f x ydxdy(),=f xu yu Jdud()()(),,,vv v


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Carl Gustave Jacobi (1804–1851), born in Berlin, discussed the quantities called Jacobians in his De


determinantibus functionalibus(On functional determinants) of 1841. The general transformation of variables in a


double integral was given by Euler in 1769.


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The integral was first evaluated by de Moivre in 1733. Laplace, following Euler, used the method described


here in 1774.

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