The components of orbital angular momentum do not commute withH.
[H,Lz] =icγ 4 [γjpj,xpy−ypx] = ̄hcγ 4 (γ 1 py−γ 2 px)
The components of spin also do not commute withH.
Σz =
[γ 1 ,γ 2 ]
2 i
=
γ 1 γ 2
i
[H,Sz] = [H,
̄h
2
Σz] =c
̄h
2
[γ 4 γjpj,γ 1 γ 2 ] =c
̄h
2
pj[γ 4 γjγ 1 γ 2 −γ 1 γ 2 γ 4 γj]
= c
̄h
2
pj[γ 4 γjγ 1 γ 2 −γ 4 γ 1 γ 2 γj] =c
̄h
2
pjγ 4 [γjγ 1 γ 2 −γ 1 γ 2 γj] = ̄hcγ 4 [γ 2 px−γ 1 py]
However, thehelicity, or spin along the direction of motion does commute.
[H,S~·~p] = [H,S~]·~p= ̄hcγ 4 ~p×~γ·~p= 0
From the above commutators [H,Lz] and [H,Sz], thecomponents of total angular momentum
do commutewithH.
[H,Jz] = [H,Lz] + [H,Sz] = ̄hcγ 4 (γ 1 py−γ 2 px) + ̄hcγ 4 [γ 2 px−γ 1 py] = 0
The Dirac equation naturallyconserves total angular momentumbut not conserve the orbital
or spin parts of it.
We will need another conserved quantity for the solution to the Hydrogen atom; something akin to
the±inj=ℓ±^12 we used in the NR solution. We can show that [H,K] = 0 for
K=γ 4 Σ~·J~−
̄h
2
γ 4.
It is related to the spin component along the total angular momentum direction. Lets compute the
commutator recalling thatHcommutes with the total angular momentum.
H = icγ 4 ~γ·~p+mc^2 γ 4
[H,K] = [H,γ 4 ](Σ~·J~−
̄h
2
) +γ 4 [H,~Σ]·J~
[H,γ 4 ] = ic[γ 4 ~γ·~p,γ 4 ] = 2ic~γ·~p
[H,Σz] = 2cγ 4 [γ 2 px−γ 1 py]
[
H,~Σ
]
= − 2 cγ 4 ~γ×~p
[H,K] = 2ic(~γ·~p)(Σ~·J~−
̄h
2
)− 2 c~γ×~p·J~
~p·~L = 0
J~ = L~+ ̄h
2
Σ~
[H,K] = 2c
(
i(~γ·~p)(Σ~·J~)−~γ×~p·J~−i
̄h
2
(~γ·~p)