ALCOHOLS FROM CARBONYL COMPOUNDS.
OXIDATION-REDUCTION AND
ORGANOMETALLIC COMPOUNDS
THE TWO ASPECTS OF THE COENZYME NADH
- The role of many of the vitamins in our diet is to become coenzymes for
enzymatic reactions.
- Coenzymes are molecules that are part of the organic machinery used by some
enzymes to catalyze reactions.
- The vitamins niacin (nicotinic acid, 菸鹼酸) and its amide niacin amide are
precursors to the coenzyme nicotinamide adenine dinucleotide.
NicotineN
N NNNH 2AdenineN
N CH^3
Niacin (Nicotinic acid)NOHONicotinamideNNH 2OO
OOH OHH H
HCH 2HAdenineO
OOH OHH H
HCH 2HP− P
OOO
−O
OC NH
2H ON+O
OOH OHH H
HCH 2HAdenineO
OOH OHH H
HCH 2HP− P
OOO
−O
OC NH
2H ONHnicotinamide adenine dinucleotide reduced nicotinamide adenine dinucleotide
NAD+ NADH