Advices For Studying Organic Chemistry

(Wang) #1
R

C NH
2

H O

N+

NAD+

1) Soybeans are one dietary source of niacin.


  1. NAD+ is the oxidized form while NADH is the reduced form of the coenzyme.

    1. NAD+ serves as an oxidizing agent.

    2. NADH is a reducing agent that acts as an electron donor and frequently as a
      biochemical source of hydride (“H–”).




12.1 INTRODUCTION



  1. Carbonyl compounds include aldehydes, ketones, carboxylic acids, and esters.


R

H

C

R

R'

C

R

HO

C

R

R'O

C
C O O O O O

The carbonyl group An aldehyde A ketone A carboxylic A carboxylate ester


12.1A STRUCTURE OF THE CARBONYL


  1. The carbonyl carbon atom is sp^2 hybridized ⇒ it and the three groups attached to
    it lie in the same plane.



  1. A trigonal plannar structure ⇒ the bond angles between the three attached atoms
    are approximately 120°.

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