Laboratory Methods of Inorganic Chemistry, 2nd English Ed. 1928
CHAPTER V. COMPOUNDS CONTAINING A COMPLEX POSITIVE COMPONENT. THE fundamental principles involved in the formation and dissociat ...
156 AMMONIUM COMPOUNDS. AMMONIUM COMPOUNDS AND SUBSTITUTED AMMONIUM COMPOUNDS. Dissociation of Ammonium Chloride. The fact that ...
HYDROXYLAMINE SULPHATE 157 and these substances interact to form hydroxylamine sulphate, and neutral sodium sulphate. The presen ...
158 SUBSTITUTED AMMONIUM COMPOUNDS. product from half its weight of hot water. Yield, 10 to 14 g. of hydroxylamine chloride. Hea ...
HYDRAZINE SULPHATE. 159 thus formed breaks down with water, essentially into sulphur dioxide, carbon dioxide, and hydrazine sulp ...
160 SUBSTITUTED AMMONIUM COMPOUNDS. about 40% of the weight of the potassium diazomethanedisul- phonate. Dependent preparation: ...
SEMICARBAZIDE HYDROCHLORIDE 161 Semicarbazide Hydrochloride. From ammonia and cyanic acid urea can be obtained, with the inter ...
162 SUBSTITUTED AMMONIUM COMPOUNDS. Millon's Base. Millon's base, Hg 2 NOH. 2 H 2 O, is formed by the action of mercuric oxide ...
METAL-AMMONIA COMPOUNDS. 163 again filtering. The solution, after being acidified with nitric acid, gives no precipitate with si ...
164 METAL-AMMONIA COMPOUNDS. pressure is known as an isotherm. With pressure constant the plot of con- centration against temper ...
METAL-AMMONIA COMPOUNDS 165 ammonia salts has led to corresponding results: ammonia is usually found in the cation.^1 Whether ot ...
166 METAL-AMMONIA COMPOUNDS Besides ammonia a number of other substances of similar nature, such as ethylene diamine and pyridin ...
• TABLE I. — COBALTIAMMONIA COMPOUNDS. Rational Name. Formula. Old Name. With Trivaknt Cation. Hexamminecobaltic Salts [Co(NH ...
O5 00 Rational Name. TABLE 2. — PLATINOAMMONIA COMPOUNDS.^1 Formula. Old Name. Tetrammineplatinous Salts [Pt(NH 3 )JX 2 Platodia ...
SILVER-AMMONIA SULPHATE. 169 tion that the constutuents of the "inner sphere" which surrounds the central metal atom are actuall ...
170 METAL-AMMONIA COMPOUNDS. dissolve the perfectly dry residue in the least amount possible of concentrated ammonia (Hood). Fil ...
HEXAMMINENICKELOUS BROMIDE. 171' The mixture becomes heated to boiling as a result of the reaction, and it should therefore be c ...
172 METAL-AMMONIA COMPOUNDS. theoretical. If desired the preparation can be carried out on a smaller scale. Carbonatotetrammine ...
CHLOROPENTAMMINECOBALTIC CHLORIDE. 173 the carbonatotetrammine salt with hydrochloric acid, there is formed, for the most part, ...
174 METAL-AMMONIA COMPOUNDS. hour, a separation of chloropentamminecobaltic chloride takes place. After cooling, filter off the ...
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