Concise Physical Chemistry

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 94 EQUILIBRIUM and GB=G◦B+RTln pB 1. 0 where the 1.0 in th ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come GENERAL FORMULATION 95 wherea, b,...c, d,...are the stoich ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 96 EQUILIBRIUM “difficulty” of the experiment and how “goo ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come VARIATION OF THE EQUILIBRIUM CONSTANT WITH TEMPERATURE 97 ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 98 EQUILIBRIUM so ⎡ ⎢ ⎢ ⎣ ∂ ( RlnKeq ) ∂ ( 1 T ) ⎤ ⎥ ⎥ ⎦ p ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come VARIATION OF THE EQUILIBRIUM CONSTANT WITH TEMPERATURE 99 ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 100 EQUILIBRIUM and lnKeq= −
rH◦ R ( 1 T ) +
rS◦ R This i ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come CHEMICAL POTENTIAL: NONIDEAL SYSTEMS 101 written Keq= fB f ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 102 EQUILIBRIUM Although the Gibbs chemical potential appl ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come FREE ENERGY AND EQUILIBRIA IN BIOCHEMICAL SYSTEMS 103 5 ′- ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 104 EQUILIBRIUM and the other producing 4 mol of ATP 2 Gly ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 105 Example 7.2 Adenosine 5′-triphos ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 106 EQUILIBRIUM pressure of N 2 O 4 (g) had dropped to 1.9 ...

c07 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 107 adenosine 5′-diphosphate ADP was ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 8 A Statistical Approach to Thermodynamics In the late nin ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come DEGENERACY AND EQUILIBRIUM 109 A(g) B(g) · · · εB · · · · ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 110 A STATISTICAL APPROACH TO THERMODYNAMICS · · · · · · · ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come DEGENERACY AND EQUILIBRIUM 111 ========== ========== ===== ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come 112 A STATISTICAL APPROACH TO THERMODYNAMICS 8.3 GIBBS FRE ...

c08 JWBS043-Rogers September 13, 2010 11:25 Printer Name: Yet to Come THE THERMODYNAMIC FUNCTIONS 113 8.4 ENTROPY AND PROBABILIT ...