Concise Physical Chemistry

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 134 THE PHASE RULE 9.5 THE GIBBS PHASE RULE Of theCmole fr ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come TWO-COMPONENT PHASE DIAGRAMS 135 The mole fraction of a tw ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 136 THE PHASE RULE A and B to come to equilibrium with its ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come COMPOUND PHASE DIAGRAMS 137 other of the components to a m ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 138 THE PHASE RULE XB T, K A B . FIGURE 9.11 A compound ph ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 139 A B C FIGURE 9.12 A ternary phas ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 140 THE PHASE RULE -1/T (K-1) -0.0037 -0.0036 -0.0035 -0.0 ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 141 A B C FIGURE 9.14 A ternary phas ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 142 THE PHASE RULE (b) What is the effect of a decrease in ...

c09 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 143 Problem 9.7 Find an area with tw ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 10 Chemical Kinetics In general, chemical thermodynamics i ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come FIRST-ORDER KINETIC RATE LAWS 145 decay per second. You ha ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 146 CHEMICAL KINETICS Some chemical reactions follow the s ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come SECOND-ORDER REACTIONS 147 ln X ln X 0 t slope = –k FIGURE ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 148 CHEMICAL KINETICS If the reactants are mixed so that t ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come OTHER REACTION ORDERS 149 10.3 OTHER REACTION ORDERS In ge ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 150 CHEMICAL KINETICS 10.3.2 Back to Kinetics: Sequential ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come OTHER REACTION ORDERS 151 which is our solution for the La ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come 152 CHEMICAL KINETICS approach to equilibrium is always le ...

c10 JWBS043-Rogers September 13, 2010 11:26 Printer Name: Yet to Come OTHER REACTION ORDERS 153 An acceptable mechanism for this ...