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NITRATION AGENTS AND METHODS MORE RARELY USED 89 isomerize to give oximes. The nitrites give lower aldehydes, ketones and lower ...

90 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES CH 3 -CH 3 + HNO 3 -> -> H 2 O + C 2 H 5 NO 2 (15) The nitration theory, which a ...

NITRATION AGENTS AND METHODS MORE RARELY USED 91 The stereo-structure, including bond distances and bond angles of vapour phase ...

(^92) CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES However, a homolytic dissociation into free radicals NO 2 is possible: N 2 O 4 < ...

NITRATION AGENTS AND METHODS MORE RARELY USED 93 (21) As a result of nitrating phenol by means of N 2 O 4 at a low temperature, ...

94 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES (5) Heterocyclic compounds are more difficult to nitrate. For example, from quinoline ...

NITRATION AGENTS AND METHODS MORE RARELY USED. 95 nitroethane, l- and 2-nitropropane). Nitrohexanes (mainly 2- and 3-nitrohexane ...

96 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Hass, Dorsky and Hodge [67] nitrated paraffins with nitrogen dioxide under pressure. T ...

NITRATION AGENTS AND METHODS MORE RARELY USED^97 Nitrosate (II) Nitro-nitrate (IIa) Nitro-nitrite (IIb) Dinitro compound (III) D ...

98 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES C 6 H 5 -CH=CH-CH=CH-C 6 H 5 + N 2 O 4 -> IX A further analogy with halogen derivat ...

NITRATION AGENTS AND METHODS MORE RARELY USED 99 (22) Numerous experiments on the action of nitrogen dioxides on olefins were ca ...

100 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES hexane and 2-nitrocyclohexyl nitrite, were not formed. Instead, the main products wer ...

NITRATION AGENTS AND METHODS MORE RARELY USED 101 Phenylacetylene reacted with N 2 O 3 to yield phenylfuroxane: (25) Petrov and ...

102 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Nitrolic acids (II) are relatively stable when R is alkyl but can lose nitrous acid w ...

NITRATION AGENTS AND METHODS MORE RARELY USED 103 2HNO 3 + N 2 O 3 <-> 2N 2 O 4 + H 2 O (d) H 2 SO 4 .qH 2 O + H 2 O = H 2 ...

104 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The nitro compound, nitrosyl chloride, and basic aluminium chloride formed a number o ...

NITRATION AGENTS AND METHODS MORE RARELY USED 105 G. B. Bachman and his co-workers [91] investigated the action of the boron tri ...

106 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Titov [34] suggested in 1941 that nitrogen pentoxide undergoes a heterolytic dissocia ...

NITRATION AGENTS AND METHODS MORE RARELY USED 107 Stevens and Emmons [82] obtained three compounds: the nitro-nitrates (I) and ( ...

108 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES A very interesting result was obtained with benzene. At room temperature nitryl chlor ...