INDEX 521
Boiling point, 203
curve, 204 , 433
elevation in a solution, 375 , 380
Bomb calorimeter, 320 , 333 , 335 – 340
Bomb calorimetry, 361 p
Boundary, 27
adiabatic, 28
diathermal, 28
Boyle temperature, 35
Brewer, Leo, 271
Bridgman, Percy, 179 , 495
Bubble-point curve, 433
Cailletet and Matthias, law of, 205
Caloric theory, 62
Calorie, 86 n
Calorimeter, 168
adiabatic, 168 – 170 , 333
bomb, 320 , 333 , 335 – 340
Bunsen ice, 341
combustion, 333
constant-pressure, 170 , 213
constant-volume, 169
continuous-flow, 173
flame, 341
heat-flow, 341
isoperibol, 171 , 333 , 334 , 341
isothermal-jacket, 171 – 173 , 333 , 334 ,
341
phase-change, 340
reaction, 333 – 335
Calorimetry
bomb, 335 , 361 p
drop, 190 p
to evaluate an equilibrium constant, 354
to measure heat capacities, 168
to measure transition enthalpies, 213
reaction, 322 , 333 – 341 , 410
Candela, 470
Caratheodory’s principle of adiabatic ́
inaccessibility, 118
Carnot
cycle, 105 , 105 – 108
engine, 105 , 105 – 108
heat pump, 108
Carnot, Sadi, 106 b
Cell
diagram, 450
electrochemical, 449
galvanic, 449
reaction, 451
with transference, 451
without liquid junction, 451
without transference, 451
Cell potential, 89 , 453
equilibrium, 89
Celsius scale, 41
Center of mass, 500
Center-of-mass frame, 54 , 58 , 499 – 502
Centigrade scale, 41
Centrifugal force, 503
Centrifuge, 274
cell, 276 – 279
Charge
electric, 452
number, 294
Chemical amount, 21 n
Chemical equation, 312
Chemical potential, 136 , 142
of an electrolyte solute, 292
of electrons, 456
as a function ofTandp, 214
of a liquid or solid, 185
of a pure substance, 181
of a solvent
from the freezing point, 370 – 372
from the osmotic coefficient, 369
from osmotic pressure, 372 – 374
of a species in a mixture, 235
standard, 257 , 269
of a gas, 182
of a gas constituent, 240
of an ion, 287
of a pure substance, 182
of a symmetrical electrolyte, 289
total, 196
Chemical process, 302
subscript for, 477
Chemical work, 136
Circuit
electrical, 86 – 88
heater, 168 , 169 , 171 , 172
ignition, 336 , 338
Clapeyron equation, 216
Clapeyron,Emile, ́ 217 b
Clausius
inequality, 118
statement of the second law, 103
Clausius, Rudolf, 102 , 103 , 109 b, 127 , 131
Clausius–Clapeyron equation, 218 , 369
CODATA, 504
Coefficient of thermal expansion, 163
Coexistence curve, 200 , 213
liquid–gas, 33