Thermodynamics and Chemistry

INDEX 526

standard, 465

Ice point, 41
Ice, high pressure forms, 203
Ideal gas, 74
equation, 23 , 33 , 74
internal pressure, 166
mixture, 239 , 241
in a gravitational field, 274 – 276
and Raoult’s law, 247
Ideal mixture, 248 , 258
mixing process, 303
and Raoult’s law, 247
Ideal solubility
of a gas, 406
of a solid, 386
Ideal-dilute solution, 252
partial molar quantities in, 255 – 256
solvent behavior in, 254 – 255 , 401
Ideal-gas temperature, 40 , 115
Ignition circuit, 336 , 338
Impossible process, 66
Independent variables, 46 , 192
of an equilibrium state, 119
number of, 198 , 420
Indicator diagram, 77
Inertial reference frame, 53 , 487 , 490
Inexact differential, 52
Inner electric potential, 452
Integral, 480
formulas, 480
line, 72 , 480
Integral enthalpy of dilution, 326
Integral enthalpy of solution, 325
Integrand, 480
Integrating factor, 122
Intensive property, 29
Interface surface, 30
Internal
friction, 91 – 94
pressure, 165 , 165 – 166 , 168
of an ideal gas, 166
resistance, 455
Internal energy, 53 , 53 – 54
of an ideal gas, 74
of mixing to form an ideal mixture, 304
partial molar, 248
International System of Units,seeSI
International temperature scale, 41
Invariant system, 199 , 419
Ionic conductor of a galvanic cell, 449
Ionic strength, 294 , 296 , 298

effect on reaction equilibrium, 409

Irreversible process, 66 , 101 , 123 – 125 ,

127 – 129

Isobaric process, 51

Isochoric process, 51

Isolated system, 28 , 48

spontaneous changes in, 127

Isoperibol calorimeter, 171 , 333 , 334 , 341

Isopiestic

process, 51

solution, 268

vapor pressure technique, 268

Isopleth, 427

Isoteniscope, 203

Isotherm, 77 , 209

Isothermal

bomb process, 335 , 337 – 338 , 340

compressibility, 163 , 210 , 218

of an ideal gas, 188 p

of a liquid or solid, 180

magnetization, 160

pressure changes, 180 – 181

of a condensed phase, 180

of an ideal gas, 180

process, 51

Isotropic phase, 30

IUPAC, 19

IUPAC Green Book, 19 , 137 , 181 , 211 ,

259 n, 324 , 351 , 453 n, 470

Joule

coefficient, 188 p

experiment, 188 p

paddle wheel, 84 – 86 , 103

Joule, James Prescott, 58 , 62 , 84 , 85 b, 86 ,

99 p, 188 p

Joule–Kelvin

coefficient, 157

experiment, 156

Joule–Thomson

coefficient, 157 , 179

experiment, 156

Kelvin (unit), 40 , 470

Kelvin, Baron of Largs, 102 , 104 , 113 , 114 b

Kelvin–Planck statement of the second law,

104 , 118

Kilogram, 470

Kinetic energy, 488

Kirchhoff equation, 323 , 338

Konowaloff’s rule, 405