INDEX 527
Lab frame, 53 , 58 , 59 , 79 , 274 , 276 , 487 ,
490 – 493 , 495 , 496 , 499 , 500
Laplace equation, 198 , 280 p
Law
of Cailletet and Matthias, 205
of rectilinear diameters, 205
scientific, 56
Le Chˆatelier’s principle, 357 , 358
Legendre transform, 137 , 141 , 160 , 484 ,
484 – 485
Lever rule, 208 , 426
for a binary phase diagram, 427
general form, 208
for one substance in two phases, 206
for partially-miscible liquids, 431
for a ternary system, 442
Lewis and Randall rule, 281 p
Lewis, Gilbert Newton, 105 , 149 , 270 b, 294
Line integral, 72 , 480
Liquid, 32
Liquid junction, 449 , 451 , 457
potential, 451 , 457
Liquidus curve, 429
for a binary system, 426
for a binary liquid–gas system, 432 – 435
for a binary solid–liquid system, 426
at high pressure, 439
Liter, 37
Local frame, 53 , 57 , 58 , 69 , 79 , 276 , 278 ,
495 , 497 , 498
nonrotating, 499 – 502
rotating, 496
Magnetic
enthalpy, 160
field, 160
flux density, 158
Magnetization, isothermal, 160
Mass, 470
meaurement of, 36 – 37
Mass fraction, 223
Maxwell relations, 140
Maxwell, James Clerk, 40
McMillan–Mayer theory, 261 n
Mean ionic activity coefficient,seeActivity
coefficient, mean ionic
Mean molar volume, 230
Melting point, 203
normal, 42
Membrane equilibrium
Donnan, 396 , 396 – 399
osmotic, 395
Membrane, semipermeable, 49 , 372
Metastable state, 50
Meter, 470
Method of intercepts, 230 , 231
Metre, 470
Microstate, 130
Milliter, 37
Minimal work principle, 91
Miscibility gap
in a binary system, 312 , 430
in a ternary system, 443
Mixing process, 302
Mixture
binary, 223
of fixed composition, 225
gas, in a gravitational field, 274 – 276
ideal, 258
and chemical potential, 248
and Raoult’s law, 247
simple, 308
Molal boiling-point elevation constant, 380
Molal freezing-point depression constant,
378
Molality, 223
standard, 253
Molar
differential reaction quantity, 316
excess quantity, 305
integral reaction quantity, 316
mass, 37
from a colligative property, 376
from sedimentation equilibrium, 279
quantity, 29 , 175
reaction quantity, 316
standard, 318
Mole, 21 , 37 , 470
Mole fraction, 222
standard, 254
Mole ratio, 224
Molecular mass, relative, 37
Molecular weight, 37Natural variables, 137 , 140 , 141
Nernst
distribution law, 394
equation, 462
heat theorem, 149
Nernst, Walther, 149 n, 150 b
Neutrality, electrical, 235 , 422
Newton’s law of cooling, 171
Newton’s law of universal gravitation, 489
Newton’s second law of motion, 70 , 197 , 487