inorganic chemistry
single-electron transfer with a strong oxidation power. Further, by choosing appropriate ligands, these complexes can act as ele ...
photocatalyst, whilefac-Re(bpy)(CO) 3 (CN) ( 8 ), which also possess an anionic ligand, cannot photocatalyze CO 2 reduction (63, ...
reduction. Conversely, many of the complexes with E1/2red<1.4V versus Ag/AgNO 3 show high photocatalytic abil- ity. Although ...
phosphine ligands and the diimine ligand (see Section II.C). This weak interaction between the ligands red-shifts the MLCT absor ...
complexes intercalated between layers of Hectorite function as hydrogen-generating photocatalysts ( 75 ). Reactions using rheniu ...
CO 2 þ2Hþþ2e!COþH 2 O ð 19 Þ Re bpyðÞðÞCO 3 Cl þ2e!½ReðbpyÞðCOÞ 3 þCl ð 20 Þ Re bpyðÞðÞCO 3 þCO 2! Re bpyðÞðÞCO 3 C ...
ReIðÞbpyðÞCO 3 Cl hi ! ReIðÞbpyðÞCO 3 hi þ Cl $ Re^0 ðÞbpyðÞCO 3 þ Cl ð 23 Þ As the active species formed by eliminati ...
it reacts with CO 2 to generate the corresponding“CO 2 adduct” (Eq. 24). Two-electron reduction of CO 2 proceeds due to a second ...
that a rhenium hydride complex is an intermediate in the path- way to this formate complex ( 60 ), but this remains speculative. ...
17-electron species that reacts directly with CO 2. For the OER species to serve these two roles (1) requires stability while (2 ...
Fig. 3). However, [RuII(dmb) 3 ]^2 þ (dmb¼4,4^0 -dimethyl-2,2^0 - bipyridine) strongly absorbs light in the visible region and h ...
S CHEME Structures and abbreviations of supramolecular photocatalysts. ...
However, photocatalytic activity was lowered in the cases ofRu (mfibpy)ReandRe(mfibpy)Ruwith conjugated bridges. This is thought ...
A hybrid material has been synthesized by covalently fixing fac-[Re(dmb)(CO) 3 (PPh 3 )]þwithin the 3.5 nm diameter pores of a s ...
REFERENCES Balzani, V. Ed.:“Supramolecular Photochemistry”; D. Reidel: Dordrecht, 1987. Balzani, V.; Juris, A.; Venturi, M.; Ca ...
Koike, K.; Okoshi, N.; Hori, H.; Takeuchi, K.; Ishitani, O.; Tsubaki, H.; Clark, I. P.; George, M. W.; Johnson, F. P. A.; Turne ...
Sato, S.; Sekine, A.; Ohashi, Y.; Ishitani, O.; Blanco-Rodriguez, A. M.; Vlcek, A. Jr.; Unno, T.; Koike, K.Inorg. Chem.2007, 46 ...
Sullivan, B. P.; Bolinger, C. M.; Conrad, D.; Vining, W. J.; Meyer, T. J.J. Chem. Soc. Chem. Commun.1985, 1414 – 1416. Fujita, ...
Inagaki, S.; Ohtani, O.; Goto, Y.; Okamoto, K.; Ikai, M.; Yamanaka, K.; Tani, T.; Okada, T.Angew. Chem. Int. Ed.2009, 48 , 4042 ...
DESIGN OF PORPHYRIN-BASED PHOTOSENSITIZERS FOR PHOTODYNAMIC THERAPY LUIS G. ARNAUT^1 Chemistry Department, University of Coimbra ...
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