BioPHYSICAL chemistry

(singke) #1
(b)

−2.0 eV =2.97 eV =4.75 × 10 −^19 J

(c)

−2.0 eV =1.55 eV =2.47 × 10 −^19 J

9.14 (a)

−2.3 eV =3.88 eV =6.2 × 10 −^19 J

(b)

−2.3 eV =2.67 eV =4.27 × 10 −^19 J

(c)

−2.3 eV =1.25 eV =2.0 × 10 −^19 J

9.15 (a)

(b)

(c)

9.16The minimal frequency corresponds to a minimal energy (hν) needed
to overcome the work function.

9.17

9.18According to classical theory, the energy is independent of frequency,
but according to quantum theory, the energy is proportional to the
frequency (E=hν).

9.19 4m^3 ν= 4 m^2 p→ 4 m^2 (−iZ∇)
Eψ(r) =− 4 iZm^2 ∇ψ(r) +V(r)ψ(r)

9.20 (a)

(b)
Δ
Δ

x
m

.

(.

==

×

×



Z

2 9

105 10

2 1 67 10

34
27

Js
kg))( ) 10

−− 10 1 =^314

ms

m

Δ

Δ

x
m

.

(.

==

×

×



Z

2 9

105 10

2 1 67 10

34
27

Js
kg))( )

.

10

−− 91 =31 4

ms

m

ψψ τ*d
Vo


λ

(. )(. )

==

hc ××−−
Φ

6 62 10 2 99 10

2

(^34) Js (^8) m s 1
..(. )


.

516101

19 495 10^7

eV J/ eV

m
××

− =×−

λ

(. )(. )

.

==

hc ××−−
Φ

6 62 10 2 99 10

20

(^34) Js (^8) m s 1
eeV J/ eV
m
××


− =×−

(. )

.

16 10 1

19 621 10^7

λ

(. )(. )

==

hc ××−−
Φ

6 62 10 2 99 10

2

(^34) Js (^8) m s 1
..(. )


.

25 1 6 10 1

19 552 10^7

eV J/ eV

m
××

− =×−

KE

hc (. )(.
=−=

××−

λ

Φ

6 62 10^34 Js 2 99 10^8 mss
m

eV
J


× −−× ×

1
35 10^719

1

160 10

)

..

KE

hc (. )(.
=−=

××−

λ

Φ

6 62 10^34 Js 2 99 10^8 mss
m

eV
J


× −−× ×

1
25 10^719

1

160 10

)

..

KE

hc (. )(.
=−=

××−

λ

Φ

6 62 10^34 Js 2 99 10^8 mss
m

eV
J


× −−× ×

1
210719

1

160 10

)

.

KE

hc (. )(.
=−=

××−

λ

Φ

6 62 10^34 Js 2 99 10^8 mss
m

eV
J


× −−× ×

1
35 10^719

1

160 10

)

..

KE

hc (. )(.
=−=

××−

λ

Φ

6 62 10^34 Js 2 99 10^8 mss
m

eV
J


× −−× ×

1
25 10^719

1

160 10

)

..

456 ANSWERS TO PROBLEMS


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