Organic Chemistry

720 CHAPTER 17 Carbonyl Compounds I

Summary of Reactions

1. Reactions of acyl halides (Section 17.8)


2. Reactions of acid anhydrides (Section 17.9)


3. Reactions of esters (Sections 17.10–17.13)

OH

O−

NHCH 3

+ CH 3 OH +

HCl

ROH

+ CH 3 NH 2 + ROH

+ H 2 O +

HCl

ROH

+ H 2 O +

HO−

ROH

O

R OR

C

O

R

C

O

R

C

O

R

C

O

R

C

O

R OR

C

O

R OR

C

O

R OR

C

OCH 3

+ CH 3 OH +

O

RCOH

+ 2 CH 3 NH 2 +

+

O

RCO− H 3 NCH 3

+ H 2 O2

O

RRO

C

O

R OCH 3

C

O

R NHCH 3

C

O

R OH

C

O

C

O

R O R

C

O

C

O

R O R

C

O

C

+ + Cl−

+ CH 3 OH + HCl

+ 2 CH 3 NH 2 +

NHCH 3

CH 3 NH 3 Cl−

+ H 2 O + HCl

+

O

R Cl

C

O

R Cl

C

O

R Cl

C

O

R Cl

C

O O

ROCH 3

CC

O

R OCH 3

C

O

R OH

C

O

R

C

O

CH 3 O−

C