interference 13, 46
matching 15
sample 1
matrix-assisted laser desorption
274
mean
experimental 28
population 28
micellar electrokinetic
chromatography (MEKC or
MECC) 183
microbore columns 159
microscopy
hot-stage 321
infrared (IR) 240, 242
migration rate, differential 120
mobile phase 120, 133, 139,
156–157
mobility 104
Moseley’s Law 214–215, 216
multidisciplinary approach 284
multiple internal reflectance (MIR)
240
multiple path effects 124, 143
multivariate techniques 52–54, 247
n+1 rule 256
n-dimensional space 53
near infrared (NIR) 238
spectrometry 247
Nernst equation 64, 110
nitrogen-phosphorous detector
(NPD) 147
normal phase 157, 166
normalization, internal 47–48, 130,
154
nuclear magnetic resonance
spectrometry (NMR)
chemical shift 261
instrumentation 248, 257–260
interpretation of proton and
carbon-13 spectra 261–269
principles 248–250
resolving power 273–274
null hypothesis 34
octadecyl silica (ODS) 159, 167
one-tailed test 35
orbitals, molecular 192
outliers 35
overtone 197
oxonium systems 114
oxygen electrode 102
paper chromatography (PC) 120
partial least squares (PLS) 53
partition 123
Law 110
ratio 110
Pascal’s triangle 256–257
pattern recognition 52
peak
areas 261–262
asymmetry 126
permittivities, relative 56
pH
control 74
definition 75
measurement 77–79
scale 75
photodiode-array detectors 163
photoluminescence 224–225
photophorescence 224–225
plate number 126
polarizability 234
polarographic methods 99
polymer 313
stability 309
population, mean and standard
deviation 28
potentiometry 66–73, 84
pre-concentrate 13
pre-treatment 13
precipitation 96
titrations 92–93
precision
overall 30–31
standard deviation 27–29
within-run and between-runs
27
principal component analysis
(PCA) 53
principal component regression
(PCR) 53
probability 31
levels 29, 32, 45, 49
probable structural units (PSU)
245
proficiency testing 19, 51
proton spectra 262–263
purification 96
purity 314
pX notation 58
pyrolysis gas chromatography
(Py-GC) 141, 151, 297
Q-test 35
quadrupole mass analyzer
272–273
qualitative analysis 1, 152–154
chromatographic 129–130
electrophoresis and
electrochromatography 187
gas chromatography 152–154
high-peformance liquid
chromatography (HPLC) 166,
173
procedures 4
thin-layer chromatography
135–136
quality
assurance (QA) 19
control (QC) 2, 18–19, 49
standards 19
quantitative analysis 1, 154
chromatographic 129–130
electrophoresis and
electrochromatography
187–188
gas chromatrography (GC) 154
high-performance liquid
chromatrography (HPLC) 166,
173
procedures 4
thin-layer chromatography
(TLC) 136
quantum numbers 191
quenching 226
Raman spectrometry seeinfrared
and Raman spectrometry
Raoult’s Law 57
reagent blank 15
red shift 229
redox
electrodes 70
equilibria 59, 88, 89
titrations 90–94
reference materials 16–17
reflectance
diffuse 240, 247
spectra 240
refractive index (RI) monitors 164
regression 53
linear 42, 43–46
resolution 127, 273–274
response ratios 47
retardation 121, 122
retention 121
reversed phase 157, 167
robustness 8
rubber 309–310
S1, singlet state 225
salt bridge 62
sample
injection 139–141, 158, 180
inlet 271
laboratory 10
loop 158–159
matrix 1, 4
pre-treatment or conditioning
13
preparation 13–14
representative 10–12
selective 11
statistical 28
storage 12–13
sampling 3, 10
saturated calomel electrode (SCE)
64
scanning electron microscope
(SEM) 216
selected ion monitoring 295
selection rules 195
selectivity coefficient 72
separations
optimization 166, 171–173
planar 122
Shewart charts 49
shielding 251–252
diamagnetic 253
significance tests 34–40
silica, thin-layer chromatography
133
size exclusion chromatography
(SEC) 124, 170
slab-gel electrophoresis 182
sodium dodecyl sulfate (SDS) 184
sodium dodecyl sulfate–
polyacrylamide gel
electrophoresis (SDS-PAGE)
182
solid phase
extraction (SPE) 13, 115–118
microextraction (SPME) 115,
118
sorbents 115
111
0111
0111
0111
0111
0
111
Index 341
