17.2 Lipase- and protease-catalyzed esterification of lipids 373
Table 4.
Lipase-catalyzed glycolipid syntheses using complexated sugars.
Lipase
Solvent/Adjuvant
Log
P
Lipid Reactand
Modified Sugar
Reference
Mucor miehei
1
C
8:0
–C
18:0
,C
18:1
;
1,2-
O
-Isopropylidene-
D
Fregapane et al., 1991
Chromob. viscosum
1
Methyl esters of C
8:0
glucofuranose;
Pseudomonas
sp.
1
C
18:0
,C
18:1
1,2:3,4-Di-
O
-isopropylidene-
D
-galactopyranose;
1,2-
O
-Isopropylidene-
D
xylofuranose
Mucor miehei
1
C
12:0
,C
18:0
,C
18:1
1,2:3,4-Di-
O
-isopropylidene-
D
-galactopyranose;
Fregapane et al., 1994
1,2-
O
-Isopropylidene-
D
xylofuranose
Mucor miehei
1
Toluene
þ
2.50
C
8:0
–C
18:0
,C
18:1
Lactose tetraacetal;
Sarney et al., 1994
Maltose triacetal
Mucor miehei
1
C
12:0
–C
18:0
,C
18:1
,
1,2-
O
-Isopropylidene-
D
Ward et al., 1997
Candida antarctica
1
C
20:4
,C
22:6
,
xylofuranose
Candida antarctica
1
2-Bromotetradecanoicacid
1,2:3,4-di-
O
-isopropylidene-
D
galactopyranose
Gao et al., 1999
Mucor miehei
1
Toluene
þ
2.50
2-Bromotetradecanoicacid
Lactose tetraacetal
Gao et al., 1999
Pseudomonas
THF/Toluene
þ
0.49/ Trifluoroethyl butanoate 4,6-
O
-Benzylidene-methyl-
a-
Panza et al., 1993
cepacia
1
(1/4, v/v)
þ
2.50
and
b
-glucopyranoside
Pseudomonas cepacia
1
THF
þ
0.49
Vinyl acetate
4,6-
O
-Benzylidene-
b
- D
-gluco/
galactopyranosides
Gridley et al., 1998
Mucor miehei
1
n-Hexane
þ
3.50
C
18:0
Fructose-phenylboronate
Schlotterbeck et al., 1993;
complex
Scheckermann et al., 1995
Mucor miehei
1
n-Hexane;n-Heptane
þ
3.50
þ
4.00
C
18:0
Glucose-phenylboronateor butylboronate complex
Oguntumein et al., 1993
Pseudomonas
sp.
t-Butanol
þ
0.80
Vinyl acrylate, C
12:0
,
Olive oil, Corn oil
Glucose- or galactose-phenylboronate complex
Ikeda and Klibanov, 1993
1
Immobilized enzymes.