Front Matter

(Tina Sui) #1
374 17 Enzymatic Synthesis and Modification of Glycolipids

Table 5.

Protease-catalyzed glycolipid syntheses.

Protease

Solvent

Log

P

Lipid reactand

Sugar

Reference

Protease N

Dimethylformamide

–1.00

Trifluoroethylcaprylate

Sucrose

Carrea et al., 1989

Alcalase

Pyridine

+ 0.71

Vinyl laurate

Sucrose

Soedjak and Spradlin, 1994

Subtilisin Carlsberg

1

Dimethylformamide

–1.00

Trichloroethyl caprylate

Sucrose

Plou et al., 1995

SubtilisinCLEC

Pyridine

+ 0.71

Vinyl laurate

Sucrose

Polat et al., 1997

Trypsin (Porcinepancreas; modified)

Dimethylformamide

–1.00

C
18 : 1

Glucose

Ampon et al., 1991

Streptomyces

sp.

Dimethylformamide

–1.00

2,2,2-Trichloroethylbutyrate,Divinyl adipate

Glucose

Shibatani et al., 1997

Streptomyces

sp.

Dimethylsulfoxideor dimethylformamide


  • 1.30– 1.00


Divinyl adipate

Glucose, Mannose,Galactose,

a
-Methyl

D-galactose

Kitagawa et al., 1999

1

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