Front Matter

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17.2 Lipase- and protease-catalyzed esterification of lipids 373

Table 4.


Lipase-catalyzed glycolipid syntheses using complexated sugars.


Lipase

Solvent/Adjuvant

Log

P

Lipid Reactand

Modified Sugar

Reference

Mucor miehei

1



C

8:0

–C

18:0

,C

18:1

;

1,2-

O

-Isopropylidene-

D





Fregapane et al., 1991

Chromob. viscosum

1

Methyl esters of C

8:0





glucofuranose;

Pseudomonas

sp.

1

C

18:0

,C

18:1

1,2:3,4-Di-

O

-isopropylidene-

D
-galactopyranose;
1,2-

O

-Isopropylidene-

D





xylofuranose

Mucor miehei

1



C

12:0

,C

18:0

,C

18:1

1,2:3,4-Di-

O

-isopropylidene-

D
-galactopyranose;

Fregapane et al., 1994

1,2-

O

-Isopropylidene-

D





xylofuranose

Mucor miehei

1

Toluene

þ

2.50

C

8:0

–C

18:0

,C

18:1

Lactose tetraacetal;

Sarney et al., 1994

Maltose triacetal

Mucor miehei

1



C

12:0

–C

18:0

,C

18:1

,

1,2-

O

-Isopropylidene-

D





Ward et al., 1997

Candida antarctica

1

C

20:4

,C

22:6

,

xylofuranose

Candida antarctica

1



2-Bromotetradecanoicacid

1,2:3,4-di-

O

-isopropylidene-

D





galactopyranose

Gao et al., 1999

Mucor miehei

1

Toluene

þ

2.50

2-Bromotetradecanoicacid

Lactose tetraacetal

Gao et al., 1999

Pseudomonas

THF/Toluene

þ

0.49/ Trifluoroethyl butanoate 4,6-

O

-Benzylidene-methyl-

a-

Panza et al., 1993

cepacia

1

(1/4, v/v)

þ

2.50

and

b
-glucopyranoside

Pseudomonas cepacia

1

THF

þ

0.49

Vinyl acetate

4,6-

O

-Benzylidene-

b


  • D


-gluco/

galactopyranosides

Gridley et al., 1998

Mucor miehei

1

n-Hexane

þ

3.50

C

18:0

Fructose-phenylboronate

Schlotterbeck et al., 1993;

complex

Scheckermann et al., 1995

Mucor miehei

1

n-Hexane;n-Heptane

þ

3.50
þ

4.00

C

18:0

Glucose-phenylboronateor butylboronate complex

Oguntumein et al., 1993

Pseudomonas

sp.

t-Butanol

þ

0.80

Vinyl acrylate, C

12:0

,

Olive oil, Corn oil

Glucose- or galactose-phenylboronate complex

Ikeda and Klibanov, 1993

1
Immobilized enzymes.
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