Front Matter

378 17 Enzymatic Synthesis and Modification of Glycolipids

Table 6.ß-Glucosidase-catalyzed glycolipid syntheses. Method 1: reverse hydrolysis; method 2: trans-
glycosylation.

ß-Glucosidase Alcohol Sugar Method Reference

Almond^1 Benzyl alcohol Glucose
Cellobiose

1

2

Marek et al., 1989

Almond^1 C 5 –C 12 Glucose 1 Vulfson et al., 1990a

Almond^1 C 5 –C 8 Methyl-ß-
glucoside,
Cellobiose,
Glucose

2

1

Vulfson et al., 1990b

Trichoderma viride C 7 ,C 8 Cellobiose 2 Shinoyama et al., 1991

Almond C 3 ,C 6 ,C 8 Glucose 1 Chahid et al., 1992

Almond C 8 Glucose 1 Ljunger et al., 1994

Almond Allyl alcohol, benzyl
alcohol

Glucose,

galactose

1 Vic and Crout, 1995

Almond 4-Hydroxybutanoic
acid-N-butylamide

Glucose

Cellobiose

1

2

Fischer et al., 1995

Pyrococcus
furiosus^1

4-Hydroxybutanoic

acid-N-butylamide

Cellobiose 2 Fischer et al., 1996

Almond,
Fusarium
oxysporum

C3–C 8 Glucose 1 Tsitsimpikou et al., 1996

Aspergillus niger C 1 ,C 2 Cellobiose 2 Yan and Liau, 1998

Almond^1 C 4 Glucose 1 Otto et al., 1998c

Almond^1 C 6 ,C 8 Glucose 1 Yi et al., 1998

Almond 2-(4-Methoxybenzyl)
-1-cyclohexanol

Glucose/

Phenyl-

ß-glucose

1/2 Zarevucka et al., 1999

Almond C 4 Glucose 1 Ismail et al., 1999b

(^1) Immobilized enzymes.