Front Matter

17.3 Glycosidase-catalyzed glycosylation of fatty alcohols with sugars 379

Table 7.Glycosidase-catalyzed glycolipid syntheses. Method 1: reverse hydrolysis; method 2: transgly-
cosylation.

Glycosidase Alcohol Sugar Method Reference

ß-Galactosidase
(Aspergillus oryzae)

C 4 Methyl-ß-

galactoside

2 Beecher et al., 1990

ß-Galactosidase
(Aspergillus oryzae)

C 4 Lactose 2 Ismail et al., 1999a

ß-Galactosidase
(Escherichia coli)

2-(4-Methoxy-

benzyl)-1-cyclo-

hexanol

Galactose/

Phenyl-ß-D-

galactose

1/2 Zarevucka et al., 1999

ß-Mannosidase
(Aspergillus niger)

C1–C 8 ß-1,4-

Mannobiose

2 Itoh and Kamiyama,

1995

ß-Mannosidase
(Rhizopus niveus)

C1–C 4 , Benzyl

alcohol

ß-1,4-

Mannobiose

2 Fujimoto et al., 1997

ß-Xylosidase
(Aspergillus niger)

C 1 –C 8 ; sec.

C3,4,6; Benzyl

alcohol;

Cyclohexanol

Xylobiose 2 Shinoyama et al., 1988;

Shinoyama et al., 1991b

Culture supernatant/
Aureobasidium
pullulans

C 8 ,C 10 , sec. C 8 ,

2-Ethylhexanol

Xylan;

Xylotetraose

2 Matsumura et al., 1996

Dried cells/
Aureobasidium
pullulans

C 8 Xylan 2 Matsumura et al., 1999c

ß-Glycosidase
(Sulfolobus
solfataricus)

C1–C 8 ;sec.C5,6,7;

2-Methyl butanol

Phenyl

ß-D-glucoside,

phenyl

ß-D-galactoside

2 Trincone et al., 1991

a-Transglucosidase
(Talaromyces duponti)

C1–C 7 Maltodextrins,

maltose

2 Bousquet et al., 1998

exo-ß-D-Glucos-
aminidase (Penicillium
funiculosum)

C 1 –C 6 ;i-C3,4;

Benzyl alcohol

Chitosan 2 Matsumura et al.,

1999a,b