Front Matter

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17.3 Glycosidase-catalyzed glycosylation of fatty alcohols with sugars 379

Table 7.Glycosidase-catalyzed glycolipid syntheses. Method 1: reverse hydrolysis; method 2: transgly-
cosylation.


Glycosidase Alcohol Sugar Method Reference


ß-Galactosidase
(Aspergillus oryzae)


C 4 Methyl-ß-
galactoside

2 Beecher et al., 1990

ß-Galactosidase
(Aspergillus oryzae)


C 4 Lactose 2 Ismail et al., 1999a

ß-Galactosidase
(Escherichia coli)


2-(4-Methoxy-
benzyl)-1-cyclo-
hexanol

Galactose/
Phenyl-ß-D-
galactose

1/2 Zarevucka et al., 1999

ß-Mannosidase
(Aspergillus niger)


C1–C 8 ß-1,4-
Mannobiose

2 Itoh and Kamiyama,
1995

ß-Mannosidase
(Rhizopus niveus)


C1–C 4 , Benzyl
alcohol

ß-1,4-
Mannobiose

2 Fujimoto et al., 1997

ß-Xylosidase
(Aspergillus niger)


C 1 –C 8 ; sec.
C3,4,6; Benzyl
alcohol;
Cyclohexanol

Xylobiose 2 Shinoyama et al., 1988;
Shinoyama et al., 1991b

Culture supernatant/
Aureobasidium
pullulans


C 8 ,C 10 , sec. C 8 ,
2-Ethylhexanol

Xylan;
Xylotetraose

2 Matsumura et al., 1996

Dried cells/
Aureobasidium
pullulans


C 8 Xylan 2 Matsumura et al., 1999c

ß-Glycosidase
(Sulfolobus
solfataricus)


C1–C 8 ;sec.C5,6,7;
2-Methyl butanol

Phenyl
ß-D-glucoside,
phenyl
ß-D-galactoside

2 Trincone et al., 1991

a-Transglucosidase
(Talaromyces duponti)


C1–C 7 Maltodextrins,
maltose

2 Bousquet et al., 1998

exo-ß-D-Glucos-
aminidase (Penicillium
funiculosum)


C 1 –C 6 ;i-C3,4;
Benzyl alcohol

Chitosan 2 Matsumura et al.,
1999a,b
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