The Chemistry Maths Book, Second Edition

(Grace) #1

122 Chapter 4Differentiation


8

In fact, developments in mathematical logic between 1920 and 1960 have led to the development of a ‘non-


standard analysis’ which involves an extension to the number system to include infinitesimals (Abraham


Robinson, Non-standard analysis, Princeton, 1996).


or


(4.33)


This is the differential of ywith respect to the variable t. Division by dtthen gives the


Chain Rule:


(4.34)


Although there have been conceptual difficulties with this type of manipulation of


differentials (infinitesimals or ‘infinitely small changes’), operations with differentials


can always be shown to duplicate methods involving finite changes (∆’s instead of d’s)


and limits.


8

4.13 Exercises


Section 4.2


1.Fory 1 = 1 x


3

, find (i)the change ∆yin ythat corresponds to change ∆xin x, (ii)∆y 2 ∆x.


2.Fory 1 = 1 x


3

, find


3.For the Langmuir isotherm find (i)the change ∆θin θthat corresponds to


change ∆pin p, (ii)


Section 4.3


Find the discontinuities of the following functions and state which are essential and which


removable. Sketch graphs to demonstrate your answers.














Section 4.4


Find the limits:







      1. lim






x


x


→ x
















0


1


3


lim


x


x


x











0


2

lim


x


x


→ x










0


2

2


3


2

x


xx−


x


x


2

1


x+ 1


lim




p→ ∆p








0


θ


θ=






Kp


1 Kp


lim




x ∆


y


→ x








0


dy


dt


dy


dx


dx


dt



dy


dy


dx


dx


dt


=×dt







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