The Chemistry Maths Book, Second Edition

(Grace) #1

Section 6.5


52.Determine a reduction formula for where nis a positive integer.


53.Show that, for integersm 1 ≥ 10 andn 1 ≥ 11 ,


54.Use the results of Exercises 52 and 53 to evaluate


55.Show that, for integersm 1 ≥ 10 andn 1 > 11 ,


Evaluate
















60.The probability that a molecule of mass min a gas at temperature Thas speed vis given


by the Maxwell–Boltzmann distribution


where kis Boltzmann’s constant. Find the average speed.


61.For the Maxwell–Boltzmann distribution in Exercise 60, find the root mean square speed


, where.


62.Line shapes in spectroscopy are sometimes analysed in terms of second moments. The


second moment of a signal centred at angular frequencyω


0

is


whereg(ω)is a shape function for the signal. Evaluate the integral for the gaussian curve


Section 6.6


Evaluate the indefinite integrals:





    1. 65.Z




()


()( )()


xx


xx x


dx


2

33


123


−+


++ +


Z


()


()()


x


xx


dx






++


2


34


Z


dx


()()xx
21 3−+

gTT()ωω=−−( ω)












21


2


2

0

2

π


exp


Z


ω

ωω ω ω


0

0

2


()()− gd


vvvv


2

0

2

=Z



fd()
v

2

vvvv=Z


0


fd()


f


m


kT


e


mkT

()vv


v

=









4


2


32

22

2

π


π


Z


0

32

2


re dr


−r

Z


0

22

2


re dr


−r

Z


0

2

2


re dr


−r

Z


0

5

π 2

5

sin xxdxcos.


ZZ


00

2

1


ππ 22

sin cos sin cos


mn m n

d


n


mn


θθθ= θ θθd








Zsin cos


54

xxdx.


ZZsin cos


sin cos


sin


mn

mn

m

d


mn


n


mn


θθθ


θθ


=















+− 11

1


θθθθcos


n

d


− 2

Zsin


n

xdx,


6.8 Exercises 189

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