The Chemistry Maths Book, Second Edition

(Grace) #1

244 Chapter 8Complex numbers


We note that the quantization of the energy of the system has arisen as a consequence


of applying the periodicity condition (periodic boundary condition) to the solutions.


We note also that the set of wave functions includes all the functions (8.45) for the


possible periodicities around a circle.


0 Exercise 48


8.7 Evaluation of integrals


Integration with respect to a complex variable is an important part of the theory


of functions of a complex variable, but is used only in advanced applications in the


physical sciences. Ordinary integration over complex functions obeys the same


rules as integration over real functions. In addition, complex functions can be used


to simplify the evaluation of certain types of integral. For example, it is shown in


Example 6.13, how the integral


can be evaluated by the method of integration by parts. An alternative, more elegant,


method is to express the trigonometric function in terms of the (complex) exponential


function. We consider the general form


Because cos 1 bxis the real part ofe


ibx

it follows that the integralIis the real part of


the integral obtained fromIby replacing cos 1 bxbye


ibx

:


The complex integral is evaluated by means of the ordinary rule for the integration of


an exponential function. Thus (ignoring the constant of integration),


and this can be resolved into its real and imaginary parts:


=






++ −


e


ab


a bx b bx i a bx b bx


ax

()


(cos sin ) (sin cos )


22









Zedxe


bx i bx


aib


()aibx ax

cos sin


+

=
















Zedx


e


aib


e


e


aib


aibx

aibx

ax

ibx

()

()

+

+

=






=






Ieedxedx


ax ibx a ib x

==


+

ReZZRe


()

I e bx dx


ax

=Z cos


Zexdx


−ax

cos

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