The Chemistry Maths Book, Second Edition

(Grace) #1

9.3 Partial differentiation 249


Each of these graphs is a planar ‘cut’ through the three-dimensional surface. In the


general case, a function of nvariables defines a ‘surface’ in an(n 1 + 1 1)-dimensional


space, and its graph as a function of one of the variables is obtained by taking a planar


cut through the representative(n 1 + 1 1)-dimensional surface.


9.3 Partial differentiation


We saw in Chapter 4 that the first derivative of a function of one variable is


interpreted graphically as the slope of a tangent line to its graph, and dynamically as


the rate of change of the function with respect to the variable. For a function of


two or more variables there exist as many independent first derivatives as there are


independent variables. For example, the function


z 1 = 1 f(x, y) 1 = 1 x


2

1 − 12 xy 1 − 13 y


2

can be differentiated with respect to variable x, with ytreated as a constant, to give the


partial derivativeof the function with respect to x


(read as ‘partial dz by dx’),


2

and with respect to yat constant xfor the partial


derivative with respect to y


The existence of partial derivatives and the validity of the operation of partial differ-


entiation are subject to the same conditions of continuity and smoothness as for the


ordinary (total) derivative. If these conditions are satisfied then the partial derivatives


of a function of two variables are defined by the limits (compare equation (4.8))


(9.2)


(9.3)


The geometric interpretation of these quantities is shown in Figure 9.3. The plane


ABC is parallel to the xz-plane, so that y 1 = 1 constant in the plane and the values of


∂z 2 ∂xfor this value of yare the slopes of the tangent lines to the curve APB. In the


same way, the plane DEF is parallel to the yz-plane, and the values of∂z 2 ∂yare




=


,+∆ − ,














z


y


fxy y fxy


y y


lim


()()


∆ 0




=


+∆ , − ,














z


x


fx xy fxy


x x


lim


()()


∆ 0




=− −


z


y


26 xy




=−


z


x


22 xy


2

The notation∂z 2 ∂xwas first used by Legendre in 1788, but began to be accepted only after Jacobi used it in


his theory of determinants in 1841.

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