The Chemistry Maths Book, Second Edition

(Grace) #1

418 Chapter 15Orthogonal expansions. Fourier analysis


and this can be used to obtain a general formula for the coefficientsc


l

in (15.3). We


multiply equation (15.3) byP


k

(x)and integrate. Then


and because, by (15.7), each integral on the right is zero except for the one withl 1 = 1 k,


only that term contributes to the sum:


Therefore


(15.8)


This important formula gives the values of the coefficientsc


l

in the expansion of a


finite continuous function of x, for|x| 1 ≤ 11 , in terms of the Legendre polynomials.


Then, for the power series ,


(15.9)


Replacement ofP


k

(x)in the integrals by its expansion in powers of x, from tabulations


like (15.4) or from the general formula (13.19), then gives the coefficientc


k

in terms


of the coefficientsa


l

.


EXAMPLE 15.1Use equation (15.9) fork 1 = 1 0 to findc


0

.


We haveP


0

1 = 1 1 so that equation (15.9) is


where


Z



+


+

+

=














=
+

1

1

1

1

1

1


2


1


xdx


x


l


l


l


l

l

if is even


00 if is oddl







caxdx


l

l

l

0

0 1

1

1


2


=


= −

+



Z


c


k


aPxxdx


k

l

lk

l

=






= −

+


21


2


0 1

1


Z ()


fx ax


l

l

l

()=


=


0


c


k


Pxfxdx


kk

=







+

21


2


1

1

Z ()()


ZZ



+


+

==






1

1

1

1

2


21


Pxfxdx c PxPxdx


k


c


kkkk

()() () ()


kk

ZZ



+


+

=

=







1

1

1

1

0

Pxfxdx Px cPx


kk

l

ll

()() () ()








=


= −

+


dx c P x P x dx


l

lkl

0 1

1


Z () ()

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