The Chemistry Maths Book, Second Edition

(Grace) #1

606 Chapter 21Probability and statistics


More generally, the binomial distribution applies to any experiment whose


outcomes can be treated as two exclusive events. These are often called ‘success’, with


probability p, and ‘failure’, with probabilityq 1 = 111 − 1 p. The probability of obtaining m


successes from ntrials is then


(21.19)


The mean, variance and standard deviation of the distribution are


(21.20)


EXAMPLE 21.6The probability that the outcome of 10 tosses of a coin consists of


mheads (and 101 − 1 mtails) is


with μ 1 = 15 , V 1 = 1 2.5, and σ 1 = 1 1.58. The corresponding binomial distribution is


compared in Table 21.5 with the relative frequenciesf


m

obtained from Table 21.2.


Table 21.5


m 0 12345678910


P


m

0.001 0.01 0.04 0.12 0.21 0.25 0.21 0.12 0.04 0.01 0.001


f


m

0.02 0.00 0.10 0.10 0.18 0.20 0.18 0.12 0.09 0.04 0.00


The mean, variance, and standard deviation of the frequency distribution are


M1= 1 4.98,V(n) 1 = 1 3.8,ands 1 = 1 1.95. The differences between theory and experiment


are due to the small size of the sample (50 sets of 10 tosses).


EXAMPLE 21.7Find the probability of throwing at least 2 ‘sixes’ in 4 throws of a


fair die.


The probability of success in one throw is , so that. The total probability of


at least two successes (two, three or four) is then


P 1 = 1 P


2

1 + 1 P


3

1 + 1 P


4

0 Exercises 12, 13


=








++= =.


4

1


6


150 20 1


171


1294


()0 132


=





































4


2


1


6


5


6


4


3


22

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34

1


6


5


6


4


4


1


6


q=


5

6

p=


1

6

P


m


m


















10 1


2


10

μσ=〈 〉=mnp Vnnp p, ()()= 11 − , = np p()−


P


n


m


pq


n


mn m


pp


m

mnm m nm

==


!


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−−

()


()1

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