The Chemistry Maths Book, Second Edition

(Grace) #1

21.6 Permutations and combinations 607


Multinomial distributions


Multinomial distributions are generalizations of the binomial distribution for


experiments that have more than two possible outcomes. Let an experiment have


kpossible outcomes,E


1

, E


2

, =, E


k

, with respective probabilitiesp


1

,p


2

, =, p


k

. Then,


the joint probability that there are n


i

occurrences of outcomeE


i

(i 1 = 11 , 2 , =, k), in n


independent trials is


(21.21)


where


is a multinomial coefficient (Section 7.3).


0 Exercises 14, 15


21.6 Permutations and combinations


The possible outcomes of tossing a coin or throwing a die are exclusive events with


equal probabilities; each of kpossible outcomes has probability 12 k. The counting of


equally-probable outcomes is important in several applications of probability theory


in the sciences and often involves the counting of the permutations and combinations


of sets of objects or events. The following theorems are some of the important results


in combinatorial theory.


2

Permutations


A set of ndifferent (distinguishable) objects (real objects, numbers, events, and so on)


may be arranged in a row in a number of ways, and each such arrangement is called


a permutationof the nobjects. For example, the three letters A, B, and Ccan be


arranged in the 6 ways


ABC, ACB, BAC, BCA, CAB, CBA


There are3! 1 = 16 permutations of 3 different objects. In general:


1.The number of permutations of ndifferent objects is n!


The first object can be put in ndifferent positions, leavingn 1 − 11 positions for the


second object (think of nboxes in a row and nballs of different colours). The first two


n


nn n


n


nn n


12 k 12 k

 










=


!


!!!


Pn n n


n


nn n


pp p


k

k

nn

k

n

k

(, , )


12

12

12

12

...,


...


=













2

An early discussion of permutations and combinations is found in the Jewish mystical Sefer Yetsirah(Book of


creation), possibly of the second century AD, in which the (unknown) author calculates the ways of arranging the


22 letters of the Hebrew alphabet, and the number of combinations taken 2 at a time. The French mathematician,


astronomer, and biblical commentator Levi ben Gerson (1288–1344) gave a derivation of the rules of combinations


in his Maasei Hoshev(Art of the calculator) in 1321. He also invented the Jacob Staff, used for centuries by sailors


to measure the angular separation of heavenly bodies.

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