HARMONIC OSCILLATOR
H= p
2
2 m+
1
2 mω
(^2) x (^2) = ̄hωA†A+ 1
2 ̄hω 10.1 En= (n+
1
2 ) ̄hω n= 0,^1 ,^2 ... 10.3
un(x) =
∑∞
k=0
akyke−y
(^2) / 2
ak+2=(k+1)(2(k−kn+2)) ak y=
√mω
̄hx
A= (
√mω
2 ̄hx+i
√p
2 m ̄hω) A
†= (√mω
2 ̄hx−i
√p
2 m ̄hω) [A,A
†] = 1
A†|n〉=
√
(n+ 1)|n+ 1〉 A|n〉=
√
(n)|n− 1 〉 u 0 (x) = (mω ̄hπ)
(^14)
e−mωx
(^2) /2 ̄h
ANGULAR MOMENTUM
[Li,Lj] =i ̄hǫijkLk [L^2 ,Li] = 0
∫
Yℓm∗Yℓ′m′dΩ =δℓℓ′δmm′
L^2 Yℓm=ℓ(ℓ+ 1) ̄h^2 Yℓm LzYℓm=m ̄hYℓm −ℓ≤m≤ℓ
L±=Lx±iLy L±Yℓm= ̄h
√
ℓ(ℓ+ 1)−m(m±1)Yℓ,m± 1
Y 00 =√^14 π Y 11 =−
√
3
8 πe
iφsinθ Y 10 =
√
3
4 π cosθ
Y 22 =
√
15
32 πe
2 iφsin (^2) θ Y 21 =−
√
15
8 πe
iφsinθcosθ Y 20 =
√
5
16 π(3 cos
(^2) θ−1)
Yℓℓ=eiℓφsinℓθ Yℓ(−m)= (−1)mYℓm∗ Yℓm(π−θ,φ+π) = (−1)ℓYℓm(θ,φ)
− ̄h^2
2 μ
[
∂^2
∂r^2 +
2
r
∂
∂r
]
Rnℓ(r) +
(
V(r) +ℓ(ℓ+1) ̄h
2
2 μr^2
)
Rnℓ(r) =ERnℓ(r)
j 0 (kr) =sin(krkr) n 0 (kr) =−cos(krkr) hℓ(1)(kr) =jℓ(kr) +inℓ(kr)
H=H 0 −~μ·B~ ~μ= 2 mce L~ ~μ= 2 gemcS~
Si= ̄h 2 σi [σi,σj] = 2iǫijkσk {σi,σj}= 0
σx=
(
0 1
1 0
)
σy=
(
0 −i
i 0
)
σz=
(
1 0
0 − 1
)
Sx= ̄h
0 √^120
√^1
2 0
√^1
2
0 √^120
Sy= ̄h
0 √−i 2 0
√i
2 0
√−i
2
0 √i 2 0
Sz= ̄h
1 0 0
0 0 0
0 0 − 1
1
HYDROGEN ATOM
H=p
2
2 μ−
Ze^2
r ψnℓm=Rnℓ(r)Yℓm(θ,φ) En=−
Z^2 α^2 μc^2
2 n^2 =−
13. 6
n^2 eV
n=nr+ℓ+ 1 a 0 =αμch ̄ ℓ= 0, 1 ,...,n− 1
Rnℓ(ρ) =ρℓ
∑∞
k=0
akρke−ρ/^2 ak+1=(k+1)(k+ℓ+1k+2−ℓn+2)ak ρ=
√
− 8 μE
̄h^2 r=
2 r
na 0
R 10 = 2(aZ 0 )
(^32)
e
−aZr
(^0) R 20 = 2( 2 Za 0 )
(^32)
(1− 2 Zra 0 )e
− 2 aZr
(^0) R 21 =√^13 ( 2 Za 0 )
(^32)
(Zra 0 )e
− 2 aZr
0
Rn,n− 1 ∝ rn−^1 e−Zr/na^0 μ=mm 11 +mm^22 〈ψnℓm|e
2
r|ψnℓm〉=
Ze^2
n^2 a 0 =
Zα^2 μc^2
n^2
H 1 =− p
4
8 m^3 c^2 H^2 =
e^2
2 m^2 c^2 r^3
S~·~L ∆E 12 =−^1
2 n^3 α
(^4) mc (^2) (^1
j+^12 −
3
4 n)
H 3 = e
(^2) gp
3 mMpc^2
S~·~I 4 πδ^3 (~r) ∆E 3 =^2 gpmα
(^4) mc 2
3 Mpn^3 (f(f+ 1)−I(I+ 1)−
3
4 )
HB= 2 eBmc(Lz+ 2Sz) ∆EB=e 2 hB ̄mc(1± 2 ℓ^1 +1)mjforj=ℓ±^12