Dictionary of Chemistry [6th Ed.]

(Brent) #1
high temperatures. It also forms
complexes with a range of oxidation
states. The element was isolated by
K. K. Klaus in 1844.
A


  • Information from the WebElements site


Rutherford, Ernest, Lord (1871–
1937) New Zealand-born British
physicist, who worked under Sir J. J.
*Thomson at Cambridge University
(1895–98). He then took up a profes-
sorship at McGill University, Canada,
and collaborated with Frederick
*Soddy in studying radioactivity. In
1899 he discovered *alpha particles
and beta particles, followed by the
discovery of *gamma radiation the
following year. In 1905, with Soddy,
he announced that radioactive
*decay involves a series of transfor-
mations. He moved to Manchester
University in 1907 and there, with
Hans Geiger and E. Marsden, devised
the alpha-particle scattering experi-
ment that led in 1911 to the discov-
ery of the atomic nucleus After
moving to Cambridge in 1919 he
achieved the artiÜcial splitting of
light atoms. In 1908 he was awarded
the Nobel Prize for chemistry.

Rutherford backscattering spec-
trometry (RBS)A technique for
analysing samples of material by
irradiation with a beam of alpha
particles and measurement of the
energies of the alpha particles after
they have been scattered by the
sample. This enables the elements
present and their amounts to be de-
termined because the energy of a
scattered alpha particle depends on
the mass of the nucleus with which
it collides. RBS is used extensively in
medicine and industry.

rutherfordium Symbol Rf. A radio-
active *transactinide element; a.n.


  1. It wasÜrst reported in 1964 at
    Dubna, near Moscow, and in 1969 it


was detected by A. Ghiorso and a
team at Berkeley, California. It can
be made by bombarding californium-
249 nuclei with carbon-12 nuclei.
A


  • Information from the WebElements site


Rutherford model The model of
an atom put forward by Ernest
*Rutherford in 1911 on the basis of
experiments on the scattering of
alpha particles. The model consisted
of a very dense positively charged nu-
cleus, with electrons orbiting round
the nucleus. This model presented a
serious difÜculty for the classical
theory of electricity and magnetism,
which predicts that the electron
should spiral into the nucleus in a
fraction of a second, radiating elec-
tromagnetic energy while doing so.
This difÜculty led to the development
of the *Bohr theory in 1913 and was
deÜnitively solved by the develop-
ment of quantum mechanics and its
application to atomic structure in the
mid-1920s.

rutileA mineral form of
titanium(IV) oxide, TiO 2.

rutile structure A type of ionic
crystal structure in which the anions
have a hexagonal close packed
arrangement with cations in half the
octahedral holes. The coordination
number of the anions is 6 and the co-
ordination number of the cations is


  1. compounds with this structures in-
    clude TiO 2 , MnO 2 , SnO 2 , MgF 2 , and
    NiF 2.
    A



  • An interactive version of the structure
    Ruybal testSee scott’s test.


Rydberg constantSymbol R. A
constant that occurs in the formulae
for atomic spectra and is related to
the binding energy between an elec-
tron and a nucleon. It is connected to
other constants by the relationship R

Rutherford, Ernest, Lord 468

r

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