Dictionary of Chemistry [6th Ed.]

(Brent) #1

= μ 02 me^4 c^3 /8h^3 , where μ 0 is the mag-


netic constant, m and e are the mass


and charge of an electron, c is the


speed of light, and h is the *Planck


constant. It has the value 1.097 × 107


m–1. It is named after the Swedish


physicist Johannes Robert Rydberg


(1854–1919), who developed a for-


mula for the spectrum of hydrogen.


Rydberg spectrumAn absorption
spectrum of a gas in the ultraviolet
region, consisting of a series of lines
that become closer together towards
shorter wavelengths, merging into a
continuous absorption region. The
absorption lines correspond to elec-
tronic transitions to successively
higher energy levels. The onset of
the continuum corresponds to pho-

469 Rydberg spectrum


r

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