2.7. MOBILE CARRIERS 53
EvacEF
Ec
ENERGYElectrons in the
conduction band
can carry currentEvacEcE EV
NERGYConduction band electrons
(density, n) are mobileHoles (density, p) are mobileMobile carrier density = n + p(a)(b)- –––––––––––––
- –––––––––––––
- ––––––
Core electrons do
not carry currentWork functionSEMICONDUCTORSMETALS- ––––
+ + +EFFigure 2.16: (a) In metals the highest occupied band is partially filled and electrons can carry
current. (b) A schematic showing the valence band and conduction band in a typical semicon-
ductor. Only electrons in the conduction band and holes in the valence band can carry current.
kF,called the Fermi vector, and a velocityvF,called the Fermi velocity as
kF =(
3 π^2 n) 1 / 3
vF =(
m 0)(
3 π^2 n) 1 / 3
(2.7.4)
It is important to note that even at 0 K, the velocity of the highest occupied state isvFand not
zero, as would be the case if we used classical statistics. At finite temperatures, the Fermi level
is approximately given by
EF(T)=EF(0)[
1 −
π^2
12(kBT)^2
(EF(0))^2]
(2.7.5)
whereEF(T)andEF(0)are the Fermi levels at temperaturesTand 0 K, respectively. In Metals
there is very little change in the Fermi level with temperature.