2.7. MOBILE CARRIERS 53
Evac
EF
Ec
ENERGY
Electrons in the
conduction band
can carry current
Evac
Ec
E EV
NERGY
Conduction band electrons
(density, n) are mobile
Holes (density, p) are mobile
Mobile carrier density = n + p
(a)
(b)
- –––––––––––––
- –––––––––––––
- ––––––
Core electrons do
not carry current
Work function
SEMICONDUCTORS
METALS
- ––––
+ + +
EF
Figure 2.16: (a) In metals the highest occupied band is partially filled and electrons can carry
current. (b) A schematic showing the valence band and conduction band in a typical semicon-
ductor. Only electrons in the conduction band and holes in the valence band can carry current.
kF,called the Fermi vector, and a velocityvF,called the Fermi velocity as
kF =
(
3 π^2 n
) 1 / 3
vF =
(
m 0
)(
3 π^2 n
) 1 / 3
(2.7.4)
It is important to note that even at 0 K, the velocity of the highest occupied state isvFand not
zero, as would be the case if we used classical statistics. At finite temperatures, the Fermi level
is approximately given by
EF(T)=EF(0)
[
1 −
π^2
12
(kBT)^2
(EF(0))^2
]
(2.7.5)
whereEF(T)andEF(0)are the Fermi levels at temperaturesTand 0 K, respectively. In Metals
there is very little change in the Fermi level with temperature.