proportional to the amount of mass (Fig. 8–42). Again taking the positive
direction of heat transfer to be to the system and the positive direction of work
transfer to be from the system, the general exergy balance relations (Eqs. 8–36
and 8–37) can be expressed for a control volume more explicitly as
(8–44)
or
(8–45)
It can also be expressed in the rate formas
(8–46)
The exergy balance relation above can be stated as the rate of exergy change
within the control volume during a process is equal to the rate of net exergy
transfer through the control volume boundary by heat, work, and mass flow
minus the rate of exergy destruction within the boundaries of the control
volume.
When the initial and final states of the control volume are specified, the
exergy change of the control volume is X 2 X 1 m 2 f 2 m 1 f 1.
Exergy Balance for Steady-Flow Systems
Most control volumes encountered in practice such as turbines, compres-
sors, nozzles, diffusers, heat exchangers, pipes, and ducts operate steadily,
and thus they experience no changes in their mass, energy, entropy, and
exergy contents as well as their volumes. Therefore,dVCV/dt 0 and
dXCV/dt0 for such systems, and the amount of exergy entering a steady-
flow system in all forms (heat, work, mass transfer) must be equal to the
amount of exergy leaving plus the exergy destroyed. Then the rate form of
the general exergy balance (Eq. 8–46) reduces for a steady-flow processto
(Fig. 8–43)
Steady-flow: (8–47)
For a single-stream(one-inlet, one-exit) steady-flow device, the relation
above further reduces to
Single-stream: (8–48)
where the subscripts 1 and 2 represent inlet and exit states,m
.
is the mass
flow rate, and the change in the flow exergy is given by Eq. 8–23 as
c 1 c 2 1 h 1 h 22 T 01 s 1 s 22
V 12 V 22
2
g 1 z 1 z 22
aa^1
T 0
Tk
bQ
#
kW
#
m
#
1 c 1 c 22 X
#
destroyed^0
aa^1
T 0
Tk
bQ
#
kW
#
a
in
m#ca
out
m#cX
#
destroyed^0
aa^1
T 0
Tk
bQ
#
kaW
#
P 0
dVCV
dt
ba
in
m#ca
out
m#cX
#
destroyed
dXCV
dt
aa^1
T 0
Tk
bQk 3 WP 01 V 2 V 124 a
in
mca
out
mcXdestroyed 1 X 2 X 12 CV
XheatXworkXmass,inXmass,outXdestroyed 1 X 2 X 12 CV
458 | Thermodynamics
Steady flow
system
Xdestroyed
Xin Xout
Heat
Work
Mass
Heat
Work
Mass
· ·
·
FIGURE 8–43
The exergy transfer to a steady-flow
system is equal to the exergy transfer
from it plus the exergy destruction
within the system.
SurroundingsSurroundings
Q
ControlControl
volumevolume
XCVCV
T
mi
ci
me
ce
W
Xworkwork
Xheatheat
FIGURE 8–42
Exergy is transferred into or out of a
control volume by mass as well as
heat and work transfer.
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