P1: OSO
ind JWBS043-Rogers September 24, 2010 12:57 Printer Name: Yet to Come
INDEX 377Spontaneous processes, 77
chemical reactions, 78
expansion, 75
heating and expansion, 75
heating, 74
mixing, 77
Stability products, 228
Standard hydrogen electrode SHE, 233
Standard state, 103
Standard states, 58
State function, 237
State functions (variables), 41, 45
State of a System, 19
State vector, 241
State, 19
Statistical approach to thermodynamics,
108
Statistical thermodynamic functions
(Irikura, 1998), 114
Statistical thermodynamic functions,
113
Statistical thermodynamics, 108
Steady-state approximation, 153
Steady-state equilibrium, 353
Stewart, 323
STO-2G of hydrogen, 325
basis set, 325, 326
STO-3G calculations on methanol, 333
Stoichiometric coefficient, 96
Stored parameters, 328
STO-2G basis for the 1s orbital of
hydrogen, 326–328
Strainless molecule, 307
Stretching a two-dimensional membrane,
166
Strong electrolytes, 208
Structure, 307
Subcritical fluids, 25
Sucrose, 199
Sulfur dioxide, 82
Sum-over-states, 10
Supercritical fluid, 25
Surface tension, 165
Surroundings, 41
Symmetry, 340
System, 19, 41Temperature dependence of the Gibbs free
energy, 88
Ternary phase diagrams, 138Thermal protein denaturation, 67
Thermal reaction, 67
Thermal wavelength, 118, 120, 123
electronic, 116
dissociation, 117
translational, 116, 118
Thermochemical cycle, 60
Thermochemistry, 56
Thermodynamic cycles, 37
Thermodynamic functions, 37, 41
Thermodynamic property, 41
Thermodynamic states and systems, 41
Thermodynamics of simple systems, 35
the first law, 35
Third law, 78
Tie line, 137, 139
Time’s arrow, 73
Tocopherols, 347
Total volume of an ideal binary solution,
130
Transition states, 313
Transition, 42
Translational levels, 119
Translational motion, 118
quantum number, 118
thermal wavelength, 118
Transport number, 209, 211
Triple point, 127
benzene, 143
Trouton’s rule, 91
Two-component phase diagrams, 134
Type 1, 135
Type II, 136
Type III, 137
Two-level equilibrium, 109, 111UHF, 329
Uncertainty principle, 238
Unit cell, 174, 180
Units, 2
Universal gas constant, 13, 17
Universe, 41, 73Valence bond theory, 239
van der Waals equation, 18
van’t Hoff equation, 98
Vapor pressure, 184, 187, 196
depression, 190
Raoult’s law, 184