Concise Physical Chemistry

P1: OSO
ind JWBS043-Rogers September 24, 2010 12:57 Printer Name: Yet to Come

376 INDEX

QCISDT, 337

Quadratic least squares, 21, 22

Quadratic real gas behavior, 32

Quantum mechanical systems, 251

Quantum molecular modeling, 318

Quantum numbers, 249, 277

Quantum rigid rotor, 290

energy levels, 291

Quantum yields, 345

experimental quantum yields, 345

Radial equation, 258

Radial node of the 2p atomic orbital,

262

Radiative decay, 161

Radioactive decay, 144

Raoult’s law, 183

Rate controlling step, 155

Ratioγ, 50–51, 55

Reaction coordinate, 73, 351

Reaction diagram, 88

Reaction mechanisms, 154

Reaction order, 149

Reaction molecularity, 155

Real gases, 18, 30

Real solutions, 185

Reciprocity relationship, 36

Redox, 234

Reduced variables, 27

Reduction potentials, 223

Reference states, 307

Regression wizard, 31

Reservoir, 72

Resistivity, 205

Resonance frequency, 291

Reversible expansion, 43

of an ideal gas, 43

Reversible processes, 42

path independence, 42

Reversible reactions, 151

RHF, 329

Roothaan, 322

Rotational symmetry, 171

Route section, 329

Salt bridge, 223

Saturated calomel electrode SCE, 229,

233

Scalar, 251

SCF Energies of atoms and ions, 281

SCF variational ionization potential for

helium, 275

Schrodinger equation, 64, 250 ̈

GAMESS, 64

Schrodinger, 237 ̈

Second law of thermodynamics, 39

Second virial coefficient, 22

as a function of temperature, 22

Second-order reactions, 147–148

Secular determinant, 268, 270

Self consistent field (SCF), 243, 275,

277

Semiempirical equation, 19

Semiempirical methods, 323

Semipermiable membrane, 191

Separable equations, 256

Sequential reactions, 150

Shell structure, 331

Shelley, 220

Shielding constant, 280

Shielding, 240

Silver, standard entropy, 80, 81

Silver–Silver chloride electrode, 227, 231,

234

Sin(x), sin(2x), and sin(3x) [0,π], 249

Single-component phase diagram, 128

Slater determinants, 279, 286

Slater orbital, 276

Slater, 282

Slater’s rules, 282

Slater-type orbitals (STO), 279, 282

oxygen, 284

nitrogen, 285

Sodium vapor, 117

Software, curve fitting, 21

Solubility product constant, 228

Solubility product, 228, 231

Solute, 184

Solution chemistry, 182

Solvent, 184

Space, 9

hyperspace, 3-, 4-, etc., 10

spherical velocity space, 12

velocity space, 12

Speed, 7

Spherical polar coordinates, 259

Spin, 278

Spin–orbit coupling, 283

Spin–spin coupling, 298

Split valence basis sets, 331