280 4 Thermodynamics and Statistical Physics
4.46 For stationary waves, in thex-direction
kxa=nxπ
ornx=kxa/π
dnx=(a/π)dkx
Similar expressions are obtained foryandzdirections.
dn=dnxdnydnz
=(a/π)^3 d^3 k
However only the first octant of number space is physically meaningful.
Therefore
dn=(1/8)(a/π)^3 d^3 k
Taking into account the two possible polarizations
dn=
2 V
(2π)^3
d^3 k=
2 V
8 π^3
. 4 πk^2 dk
Butk=
ω
c
;dk=dω/c
∴dn=
Vω^2 dω
π^2 c^3
4.47n!=n(n−1)(n−2)...(4)(3)(2)
Take the natural logarithm of n!
lnn!=ln 2+ln 3+ln 4+···+ln(n−2)+ln(n−1)+lnn
=Σnn= 1 lnn
=
∫n
1
lnndn
=nlnn−n+ 1
≈nlnn−n
where we have neglected 1 forn 1
4.48 p(E)=(2J+1)e−J(J+1)
(^2) / 2 ikT
The maximum value ofp(E) is found by setting dp(E)/dJ= 0
[
2 −
(2J+1)^2 ^2
2 I 0 kT
]
e−J(J+1)
(^2) / 2 I 0 kT
= 0
Since the exponential factor will be zero only forJ=∞,
[
2 −
(2J+1)^2 ^2
2 I 0 kT
]
= 0
Solving forJ, we get
Jmax=
√
I 0 kT