PHYSICAL CHEMISTRY IN BRIEF
wang
(Wang)
#1
CHAP. 8: CHEMICAL EQUILIBRIUM [CONTENTS] 241
Reactions in the
St.state ai K
◦ φixip
pst
∏k
i=1
φνiinνii
(
p
pst
∑k
i=1ni
)∆ν
=
∏k
i=1
φνiipνii
(
1
pst
)∆ν
∑k
i=1ni
∏k
i=1
(
φini
φ•i
)νi(
1
∑k
i=1ni
)∆ν
[c] φici
cst
(
1
RT cst
)∆ν∏k
i=1
fiνi=
∏k
i=1
φνii
(
ci
cst
)νi
Reactions in the
St.state ai K
γνiinνii
(
1
∑k
i=1ni
)∆ν
[x] γ[x]
i xi
∏k
i=1
(
γ
[x]
i
)νi
nνii
(
1
∑k
i=1ni
)∆ν
[c] γ[c]
i
ci
cst
∏k
i=1
(
γi[c]
)νi
cνii
(
1
cst
)∆ν
[m] γ[m]
i
mi
mst
∏k
i=1
(
γ[im]
)νi
mνii
(
1
mst
)∆ν
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