BioPHYSICAL chemistry

11.6

11.7

11.8

11.9

11.10

11.11

11.12

11.13

11.14 221 2222

x

Ne x

x x

αα

⎛ α

⎝

⎜⎜

⎞

⎠

⎟⎟

⎛

⎝

⎜⎜

⎞

⎠

− ⎟⎟

−∞

+∞

∫ ()()

/ (()Nex/ x

1

−^222 α d

()()()Ne 0 −xx^22 //^22 x Ne 0 222 x

−∞

+∞

−

∫

ααd

DO2Hμλ= ...λ 2 O

×

===

16 2

18

mmHH 178 138 4 11 μm

HO

HO /

DO

HO

2

16 1

17

094 2

2

μ ω^2

ω

μ

=.

×

mm==

k

HH kk/

μDO 2

178

094

138

.

.

=.

Peyey==//yy

∞

−−

∞

∫∫

11

12

1

12

1

22

απ

α

π

dd

ν

ν

2 21

2

m

m

km

km

==

/

/

A== −

ν

c

1087 cm^1

ν

πμ π.

==.

×

=

−

−

1

2

1

2

500

119 10

326

1

26

k Nm

kg

× 1013 s−^1

μ=.

+

=

×

+

=×

mm

mm

CO m

CO

p

13 16

13 16

119 10 0 −^26 kg

A== −

ν

c

1111 cm^1

ν

πμ π.

==.

×

=

−

−

1

2

1

2

500

114 10

333

1

26

k Nm

kg

× 1013 s−^1

μ=.

+

=

×

+

=×

mm

mm

CO m

CO

p

12 16

12 16

114 10−^26 kg

ν

π.

=.

×

=×

−

−

(^1) −
2

600

167 10

95 10

1

27

Nm 13

kg

s^11

μ=.

+

=

×

+

=×

mm

mm

CO m

CO

p

13 16

13 16

119 10−^26 kg

ANSWERS TO PROBLEMS 463

9781405124362_5_end.qxd 4/29/08 9:17 Page 463