BioPHYSICAL chemistry

(singke) #1
11.15

The term in the left parentheses is:

so the term on the right-hand side must be zero, yielding

11.16 (a)

(b)

11.17

If B << A, the wavefunctions will be the same as those for the
harmonic oscillator.

11.18

−+++−



⎜⎜



⎟⎟

Z

222

2
2

(^1222)
mx
x
k
x
k
x
d
d
ψ() () ()ψψψ()xEx= ()


−++=−

Z^22

2

2
2 mx

xAxBe xExx

d
d

ψψψ() ( ) () ()

ν
ν

ρ
ρ

16
15

8

7

O 097

O

/

/

()

()

==.

km
km

μ ρρ

()()

=.

+

=

15 15

15 15

mm 75

μ ρρ

()()

=

+

+

+

=

mm
mm

(^12) mm
12


16 16

16 16

8

E

mm

mk k

(^0) m
2
2
2
2
12
22 2
/




⎜⎜



⎟⎟ =




ZZ

Z

Z

α ⎜⎜



⎟⎟ =

12

2

/

−+=−



⎜⎜



⎟⎟+=

ZZ

Z

2
4

2
222 m^220

k
m

mk k
α

ψ

(^0) αα
2
2
4
2
()xx 222 m 2 0
k
m


−+ E



⎜⎜



⎟⎟+−



ZZ

⎜⎜⎜



⎟⎟









= 0

−−



⎜⎜



⎟⎟








⎟+

Z^2

0

2
42

2
2

1

m 2

x

xkx
ψ
αα

() ψψψ 000 ()xEx= ()

=−



⎜⎜



ψ() ⎟⎟

(^0) αα
2
42


1

x
x

d
d

d
d

2
2 002

2
0

22
x

xN
x

x
ψ eNx
α

()=−⎛ /α

⎜⎜



− ⎟⎟= ee
−x x



⎜⎜



⎟⎟

222 2
42

/α^1
αα

d
d

d
x d

xN
x

eNe
xxx
ψ
α

αα
00
2
0
2
2

()==−^22 //^22 ⎛


−−⎜⎜




⎟⎟

464 ANSWERS TO PROBLEMS


9781405124362_5_end.qxd 4/29/08 9:17 Page 464

Free download pdf